NDLI: Selective Oxidation of Methanol to Formaldehyde Using Modified Iron-Molybdate Catalysts

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Selective Oxidation of Methanol to Formaldehyde Using Modified Iron-Molybdate Catalysts

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Selective Oxidation of Methanol to Formaldehyde Using Modified Iron-Molybdate Catalysts

Content Provider	Springer Nature Link
Author	Kim, Tae Hwan Ramachandra, B. Choi, Jung Sik Saidutta, M. B. Choo, Ko Yeon Song, Sun Dal Rhee, Young Woo
Copyright Year	2004
Abstract	Methanol selective oxidation to formaldehyde over a modified Fe-Mo catalyst with two different stoichiometric (Mo/Fe atomic ratio = 1.5 and 3.0) was studied experimentally in a fixed bed reactor over a wide range of reaction conditions. The physicochemical characterization of the prepared catalysts provides evidence that Fe2(MoO4)3 is in fact the active phase of the catalyst. The experimental results of conversion of methanol and selectivity towards formaldehyde for various residence times were studied. The results showed that as the residence time increases the yield of formaldehyde decreases. Selectivity of formaldehyde decreases with increase in residence time. This result is attributable to subsequent oxidation of formaldehyde to carbon monoxide due to longer residence time.
Starting Page	161
Ending Page	165
Page Count	5
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	98
Issue Number	2-3
e-ISSN	1572879X
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2004-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Physical Chemistry Industrial Chemistry/Chemical Engineering Catalysis Pharmacy
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

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