NDLI: Structural change of Cu/ZnO by reduction of ZnO in Cu/ZnO with methanol

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Structural change of Cu/ZnO by reduction of ZnO in Cu/ZnO with methanol

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Structural change of Cu/ZnO by reduction of ZnO in Cu/ZnO with methanol

Content Provider	Springer Nature Link
Author	Jung, Kwang Deog Joo, Oh Shim Han, Sung Hwan
Copyright Year	2000
Abstract	The reducibility of ZnO was investigated in the temperature range of 523–623 K in a stream of a reducing agent such as H2, CO, and methanol. ZnO was reduced only in the presence of copper in the vicinity of ZnO with CO and methanol, but it was not reduced with H2. Methanol was a stronger reducing agent in the reduction of ZnO than CO, while CO was stronger in the reduction of CuO than methanol. Two types of brass were observed resulting from the reduction of ZnO in the Cu/ZnO sample by XRD. Zanghengite brass started to be formed at 573 K in addition to α-brass which was observed at the temperature above 523 K in the temperature range of 523–623 K during the ZnO reduction with methanol. The carbon monoxide chemisorption showed that the copper surface areas decreased during the reduction of ZnO with methanol.
Starting Page	49
Ending Page	54
Page Count	6
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	68
Issue Number	1-2
e-ISSN	1572879X
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2000-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Physical Chemistry Industrial Chemistry/Chemical Engineering Catalysis Pharmacy
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

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