NDLI: Magnesium Aluminum Spinel as an Acid–Base Catalyst for Transesterification of Diethyl Carbonate with Dimethyl Carbonate

Content Provider	Springer Nature Link
Author	Wang, Jun Han, Lu Wang, Shuping Zhang, Jingcai Yang, Yanzhao
Copyright Year	2014
Abstract	Mesoporous MgAl2O4 spinel (MAO), prepared via one-pot evaporation induced self-assembly strategy, was reported here as an acid–base bifunctionalization catalyst for the reaction for ethyl methyl carbonate from dimethyl carbonate and diethyl carbonate. The physical/chemical properties of MgAl2O4 were characterized by X-ray powder diffraction, N2 adsorption–desorption, temperature programmed desorption and Fourier transform infrared. The effects to the reaction by adjusting the catalyst amount and reaction time were tested. The transesterification induced by MAO is much faster, and meantime, the thermal stability of MAO is much higher. Moreover, the catalyst can be used directly after filtration without drying and reused for at least five times with only 1.2 % loss in catalytic activity.MgAl2O4 as an acid–base catalyst was synthesized, characterized and successfully applied for the transesterification of DMC with DEC synthesizing EMC.
Starting Page	1602
Ending Page	1608
Page Count	7
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	144
Issue Number	9
e-ISSN	1572879X
Language	English
Publisher	Springer US
Publisher Date	2014-06-21
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Heterogeneous Acid catalysis Base catalysis Ethyl methyl carbonate Magnesium aluminum spinel Catalysis Industrial Chemistry/Chemical Engineering Organometallic Chemistry Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

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