NDLI: Characteristics and Catalytic Properties of Mesocellular Foam Silica Supported Pd Nanoparticles in the Liquid-Phase Selective Hydrogenation of Phenylacetylene

Content Provider	Springer Nature Link
Author	Na Chiangmai, Chayanin Tiengchad, Napaporn Kittisakmontree, Prathan Mekasuwandumrong, Okorn Powell, Jonathan Panprat, Joongjai
Copyright Year	2011
Abstract	An ultra-large pore mesocellular foam silica (MCF) was employed as a support for preparation of supported Pd catalysts for the liquid-phase selective hydrogenation of phenylacetylene. The catalysts were prepared by three different routes: (i) incipient wetness impregnation using Pd(II)acetate solution (Pd/MCF-imp), (ii) impregnation of colloidal Pd nanoparticles obtained by the solvent reduction method (Pd/MCF-col), and (iii) in situ synthesis of MCF in the presence of the Pd colloid (Pd/MCF-ss). The conventional impregnation method resulted in more agglomeration of Pd particles and partial collapse of MCF structure, hence the Pd/MCF-imp exhibited the lowest selectivity towards styrene at total conversion of phenylacetylene. Only the Pd/MCF-ss, in which most of the Pd nanoparticles were encapsulated by the silica matrix, was found to retain high styrene selectivity (>80%) after complete conversion of phenylacetylene. Comparing to the other highly efficient Pd catalysts reported in the literature under similar reaction conditions, it can be emphasized that coverage of Pd surface by the support produces great beneficial effect for enhancing styrene selectivity, regardless of the type of supports used (i.e., TiO2, carbon nanotubes, or mesostructured silica).The direct incorporation of palladium nanoparticles before hydrolysis of the silica precursor during the synthesis of mesocellular foam silica (Pd/MCF-ss) resulted in superior catalytic performance in the selective hydrogenation of phenylacetylene, comparing to those obtained via impregnation of Pd acetate solution (Pd/MCF-imp) and deposition of Pd colloid (Pd/MCF-col). High styrene selectivity (> 80%) was retained after complete conversion of phenylacetylene over the Pd/MCF-ss.
Starting Page	1149
Ending Page	1155
Page Count	7
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	141
Issue Number	8
e-ISSN	1572879X
Language	English
Publisher	Springer US
Publisher Date	2011-04-07
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Mesocellular foam silica Pd nanoparticles Phenylacetylene Hydrogenation Industrial Chemistry/Chemical Engineering Catalysis Physical Chemistry Organometallic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

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