NDLI: Hydrogenation of 2-Ethylhexenal Using Supported-Metal Catalysts for Production of 2-Ethylhexanol

Content Provider	Springer Nature Link
Author	Liu, Guoxiu Liu, Shiwei Liu, Siyuan Yu, Shitao Li, Lu Liu, Fusheng Xie, Congxia Song, Xiuyan
Copyright Year	2016
Abstract	The catalytic hydrogenation of 2-ethylhexenal was investigated over Pd supported on ZrO2, CeO2, Al2O3, MCM-41, MAS-7 and SBA-15. The activities and the selectivities of the catalysts were strongly affected by the nature of the support. Pd/ZrO2 had an excellent catalytic performance for the hydrogenation. The superior dispersion of Pd on the support ZrO2, and the stable structure of active components on ZrO2 as well as the synergistic effect of the bifunctional metal-support interaction enhanced the catalytic performance of Pd/ZrO2. The conversion of 2-ethylhexenal and the selectivity for 2-ethylhexanol were 100 and 99.1% respectively when the reaction was carried out at 240 °C for 7 h. The product was easily separated from the catalyst and the catalyst was of good reusability when it was repeated six times. In addition, the aggregation of Pd nanoparticles and the coking of ZrO2 the catalysts were the main cause for the catalyst deactivation.
Starting Page	987
Ending Page	995
Page Count	9
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	147
Issue Number	4
e-ISSN	1572879X
Language	English
Publisher	Springer US
Publisher Date	2017-02-28
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Hydrogenation Catalysis 2-ethylhexenal 2-ethylhexanol Industrial Chemistry/Chemical Engineering Organometallic Chemistry Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

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