NDLI: Synthesis, characterization and cyclohexene hydrogenation activity of high surface area molybdenum disulfide catalysts

Content Provider	Springer Nature Link
Author	Soto Puente, M. Valle, M. Flores Aqui, Eric Avalos Borja, M. Fuentes, S. Cruz Reyes, J.
Copyright Year	2007
Abstract	An ammonium tetrathiomolybdate (ATTM) catalyst precursor is synthesized and then thermally decomposed at different temperatures in N2 or H2 atmosphere. Characterization of the resulting compounds by powder X-ray diffraction (XRD) and surface area analysis indicates the formation of MoS2–2H with a surface area of 5–9 m2/g. When ATTM is treated with cetyltrimethylammonium chloride and then decomposed in N2 at 723 K, the resulting material has a surface area nearing 200 m2/g. If treatment also includes hydrazine, the surface area of the resulting MoS2–2H reaches 215 m2/g. Analysis by XRD and electron microscopy shows a noticeable dispersion in the layers of the resulting MoS2. The catalytic activity of the materials is tested in a batch reactor for cyclohexene hydrogenation, where the highest activity sulfides are those obtained by thermal decomposition of the chemically treated precursors in N2.
Starting Page	170
Ending Page	175
Page Count	6
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	113
Issue Number	3-4
e-ISSN	1572879X
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2007-02-02
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	high surface area MoS2 hydrogenation cyclohexene Pharmacy Industrial Chemistry/Chemical Engineering Physical Chemistry Catalysis
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

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