NDLI: Electrochemical Promotion of Propane and Methane Oxidation on Sputtered Pd Catalyst-Electrodes Deposited on YSZ

Content Provider	Springer Nature Link
Author	Peng ont, S. Praserthdam, P. Matei, F. Ciuparu, D. Brosda, S. Vayenas, C. G.
Copyright Year	2012
Abstract	The microstructure and electrochemical promotion of thin Pd catalyst-electrodes deposited on yttria-stabilized zirconia and prepared by sputter-deposition has been studied for the complete oxidation of propane and methane using steady state catalytic measurements in conjunction to electrochemical studies under lean conditions and at temperatures from 320 to 450 °C. It was found that propane oxidation is favoured on the metallic Pd film, while methane oxidation is enhanced after partial oxidation of the sputtered film in the course of the experiments. The observed rate changes under anodic polarization were strongly non-Faradaic and exceeded the electrocatalytic rate, I/2F, of O2− supply to the catalyst by up to a factor of 150 for methane and 250 for propane combustion. The catalytic rate increases only moderately by up to a factor of 2 and 3, respectively. For both reactions the catalyst-electrodes exhibit electrophobic behaviour, i.e. the rate increases with anodic polarization and decreases slightly with cathodic polarization.
Starting Page	1336
Ending Page	1343
Page Count	8
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	142
Issue Number	11
e-ISSN	1572879X
Language	English
Publisher	Springer US
Publisher Date	2012-09-29
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Methane oxidation Propane oxidation Electrochemical promotion Pd catalyst-electrode Sputtered catalyst-electrodes Physical Chemistry Organometallic Chemistry Catalysis Industrial Chemistry/Chemical Engineering
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Electrochemical promotion of deep oxidation of methane on Pd/YSZ

Electrochemical promotion of the oxidation of propane on Pt/YSZ and Rh/YSZ catalyst-electrodes

Electrochemical promotion of propane oxidation over Pd, Ir, and Ru catalyst-electrodes deposited on YSZ

Electrochemical investigation of O$_{2}$-exposed Pd electrodes supported on YSZ

Reaction Kinetic-Induced Changes in the Electrochemically Promoted C2H4 Oxidation on Pt/YSZ

Electrochemical promotion in O$^{2−}$ cells during propane oxidation

The role of TiO$_{2}$ layers deposited on YSZ on the electrochemical promotion of C$_{2}$H$_{4}$ oxidation on Pt

Effect of Pt coverage in Pt-deposited Pd nanostructure electrodes on electrochemical properties

Electrochemical modification of the catalytic activity of TiO$_{2}$/YSZ supported rhodium films

Electrochemical Promotion of Propane and Methane Oxidation on Sputtered Pd Catalyst-Electrodes Deposited on YSZ

Similar Documents

Electrochemical promotion of deep oxidation of methane on Pd/YSZ

Electrochemical promotion of the oxidation of propane on Pt/YSZ and Rh/YSZ catalyst-electrodes

Electrochemical promotion of propane oxidation over Pd, Ir, and Ru catalyst-electrodes deposited on YSZ

Electrochemical investigation of O$_{2}$-exposed Pd electrodes supported on YSZ

Reaction Kinetic-Induced Changes in the Electrochemically Promoted C2H4 Oxidation on Pt/YSZ

Electrochemical promotion in O$^{2−}$ cells during propane oxidation

The role of TiO$_{2}$ layers deposited on YSZ on the electrochemical promotion of C$_{2}$H$_{4}$ oxidation on Pt

Effect of Pt coverage in Pt-deposited Pd nanostructure electrodes on electrochemical properties

Electrochemical modification of the catalytic activity of TiO$_{2}$/YSZ supported rhodium films

Electrochemical Promotion of Propane and Methane Oxidation on Sputtered Pd Catalyst-Electrodes Deposited on YSZ