NDLI: Redox and catalytic behaviors of chromium oxide supported on zirconia

Content Provider	Springer Nature Link
Author	Sohn, Jong Rack Ryu, Sam Gon
Copyright Year	2001
Abstract	Chromium oxide supported on zirconia was prepared by dry impregnation of powdered Zr(OH)4with an aqueous solution of (NH4)2CrO4 followed by calcining in air. Upon the addition of only a small amount of chromium oxide (1 wt% Cr) to ZrO2, both the acidity and acid strength of the catalyst increased remarkably. The redox and catalytic behaviors of the samples were investigated through XPS and the reaction of cumene using a pulse technique. It was found that Cr6+ species existing on the surface of catalyst were responsible for the formation of strong acid sites and the catalytic activity for cracking of cumene. However, the Cr6+ species were easily reduced to Cr3+ species during the catalytic reaction of cumene and the reduced Cr3+ species were active for α-methylstyrene formation due to the dehydrogenation of cumene. The reduced Cr3+ species could be reoxidized by treatment with O2 and subsequently the reoxidized catalyst exhibited catalytic activity for the cracking reaction of cumene.
Starting Page	105
Ending Page	110
Page Count	6
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	74
Issue Number	1-2
e-ISSN	1572879X
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2001-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Physical Chemistry Industrial Chemistry/Chemical Engineering Pharmacy
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Redox Isotherms for Vanadia Supported on Zirconia

In situ investigation of active sites in zirconia-supported chromium oxide catalysts during the aromatization of n-octane

Effect of supports on catalytic activity of chromium oxide-based catalysts in the dehydrogenation of propane with CO2

Catalytic Behavior of Alumina-Promoted Sulfated Zirconia Supported on Mesoporous Silica in Butane Isomerization

Catalytic Properties of Cr2O3 Doped with MgO Supported on MgF2 and Al2O3

Structural change of palladium particles supported on cerium oxide in catalytic methanol synthesis

Effects of Zirconia Phase on the Synthesis of Methanol over Zirconia-Supported Copper

Chromium Oxide Supported on Mesoporous SBA-15 as Propane Dehydrogenation and Oxidative Dehydrogenation Catalysts

Catalytic behaviour of chromium supported mesoporous MCM‐41 silica in the oxidative dehydrogenation of propane

Redox and catalytic behaviors of chromium oxide supported on zirconia

Similar Documents

Redox Isotherms for Vanadia Supported on Zirconia

In situ investigation of active sites in zirconia-supported chromium oxide catalysts during the aromatization of n-octane

Effect of supports on catalytic activity of chromium oxide-based catalysts in the dehydrogenation of propane with CO2

Catalytic Behavior of Alumina-Promoted Sulfated Zirconia Supported on Mesoporous Silica in Butane Isomerization

Catalytic Properties of Cr2O3 Doped with MgO Supported on MgF2 and Al2O3

Structural change of palladium particles supported on cerium oxide in catalytic methanol synthesis

Effects of Zirconia Phase on the Synthesis of Methanol over Zirconia-Supported Copper

Chromium Oxide Supported on Mesoporous SBA-15 as Propane Dehydrogenation and Oxidative Dehydrogenation Catalysts

Catalytic behaviour of chromium supported mesoporous MCM‐41 silica in the oxidative dehydrogenation of propane

Redox and catalytic behaviors of chromium oxide supported on zirconia