NDLI: Y-Faujasite Encapsulated Co Clusters: Synthesis, Characterization and Theoretical Model as Probe of the Methane Homologation

Content Provider	Springer Nature Link
Author	Shen, James G.C. Ma, Qisheng
Copyright Year	2004
Abstract	The adsorption of Co2(CO)8 onto the dehydrated Y-faujasite powder under an N2 atmosphere and onto the tetrahydrofuran slurry of Y-faujasite under a mixed CO and H2 atmosphere predominately yielded supported Co4(CO)12 and supported Co6(CO)16, respectively. The molecular cobalt-carbonyl clusters and their decarbonylated products have been structurally characterized by extended X-ray absorption fine structure (EXAFS). The decarbonylated sample a possesses a cluster of two Co atoms and the decarbonylated sample b has a cluster phase of three Co atoms. The decarbonylated sample a exhibited higher CH4 conversion and C2+ selectivity (C2+ selectivity = ∑nC n(n = 2–5)/∑nC n (n = 1–5) * 100%) in comparison with the decarbonylated sample b in methane homologation. A density functional theory (DFT) model was employed to calculate Co clusters adsorbed on a silica substrate which simulates Y-faujasite encapsulated Co clusters. The structural geometries, net spin electronic charge densities, energies of the metal–silica and metal–metal interactions in stable geometries are discussed and used to interpret the cluster size dependence of the catalytic activity and selectivity to C 2+ hydrocarbons in the methane homologation.
Starting Page	19
Ending Page	27
Page Count	9
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	93
Issue Number	1-2
e-ISSN	1572879X
Language	English
Publisher	Kluwer Academic Publishers
Publisher Date	2004-01-01
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Physical Chemistry Industrial Chemistry/Chemical Engineering Pharmacy
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

New Preparation Method of CdS Clusters Encapsulated in Y-Type Zeolites

Hexairidium carbonyl clusters in the micropores of faujasite zeolites: evidence from transmission electron microscopy

Lithium ion-exchanged zeolite faujasite as support of iron catalyst for Fischer-Tropsch synthesis

Catalysis for Synthesis Gas Formation from Reforming of Methane

Zeolite-Y encapsulated metal complexes of cobalt(II) as catalyst for the hydroxylation of phenol

Brief Overview of the Partial Oxidation of Methane to Synthesis Gas

Partial oxidation of methane to synthesis gas over α-Al2O3-supported bimetallic Pt–Co catalysts

Methane Transformation using Light Gasoline as Co-Reactant over Zn/H-ZSM11

Hydrolysis of methyl α- and β-D-glucopyranosides in the presence of a dealuminated H-Y faujasite

Y-Faujasite Encapsulated Co Clusters: Synthesis, Characterization and Theoretical Model as Probe of the Methane Homologation

Similar Documents

New Preparation Method of CdS Clusters Encapsulated in Y-Type Zeolites

Hexairidium carbonyl clusters in the micropores of faujasite zeolites: evidence from transmission electron microscopy

Lithium ion-exchanged zeolite faujasite as support of iron catalyst for Fischer-Tropsch synthesis

Catalysis for Synthesis Gas Formation from Reforming of Methane

Zeolite-Y encapsulated metal complexes of cobalt(II) as catalyst for the hydroxylation of phenol

Brief Overview of the Partial Oxidation of Methane to Synthesis Gas

Partial oxidation of methane to synthesis gas over α-Al2O3-supported bimetallic Pt–Co catalysts

Methane Transformation using Light Gasoline as Co-Reactant over Zn/H-ZSM11

Hydrolysis of methyl α- and β-D-glucopyranosides in the presence of a dealuminated H-Y faujasite

Y-Faujasite Encapsulated Co Clusters: Synthesis, Characterization and Theoretical Model as Probe of the Methane Homologation