NDLI: Preparation of a Sulfonated Porous Carbon Catalyst with High Specific Surface Area

Content Provider	Springer Nature Link
Author	Kita, Masaaki Arai, Keisuke Kodama, Atsushi Kousaka, Tsutomu Nakajima, Kiyotaka Hayashi, Shigebu Hara, Michikazu
Copyright Year	2009
Abstract	A sulfonated (SO3H-bearing) carbon catalyst with mesoporous structure and high specific surface area is successfully prepared by impregnating the cellulosic precursor (wood powder) with ZnCl2 prior to activation and sulfonation. The specific surface area of the porous carbon catalyst thus prepared is also found to increase with carbonization temperature to a maximum of 1,560 m2 g−1 at ca. 773 K. Structural analyses reveal that the porous carbon catalysts carbonized at temperatures higher than 723 K contain high densities of micro- and mesopores. The porous carbon catalyst exhibits high catalytic performance for the esterification of acetic acid (343 K), the activity for which is dependent only on the acid density. The porous carbon catalyst also exhibits high catalytic activity for the benzylation of toluene, whereas non-porous sulfonated carbon has very limited activity for this reaction. The activity for the benzylation of toluene is dependent on both the specific surface area and the acid density of the sulfonated porous carbon catalyst.
Starting Page	242
Ending Page	249
Page Count	8
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	131
Issue Number	1-2
e-ISSN	1572879X
Language	English
Publisher	Springer US
Publisher Date	2009-06-23
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Solid acid Porous carbon ZnCl2 Hydrophobic acid-catalyzed reaction Pharmacy Industrial Chemistry/Chemical Engineering Physical Chemistry Catalysis
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Hydrolysis of sugars catalyzed by water-tolerant sulfonated mesoporous silicas

Preparation and catalytic performance of a carbon-based solid acid catalyst with high specific surface area

Synthesis of Sulfonated Carbon Nanocage and Its Performance as Solid Acid Catalyst

A Novel Sulfonated Carbon Composite Solid Acid Catalyst for Biodiesel Synthesis

Template Preparation of Highly Active and Selective Cu–Cr Catalysts with High Surface Area for Glycerol Hydrogenolysis

Facile Preparation of Ionic Liquid Functionalized Magnetic Nano-Solid Acid Catalysts for Acetalization Reaction

An Efficient and Ecofriendly WOx–ZrO2 Solid Acid Catalyst for Classical Mannich Reaction

Zirconium Phosphate with a High Surface Area as a Water-Tolerant Solid Acid

Hydrolysis of Cellulose Selectively into Glucose Over Sulfonated Activated-Carbon Catalyst Under Hydrothermal Conditions

Preparation of a Sulfonated Porous Carbon Catalyst with High Specific Surface Area

Similar Documents

Hydrolysis of sugars catalyzed by water-tolerant sulfonated mesoporous silicas

Preparation and catalytic performance of a carbon-based solid acid catalyst with high specific surface area

Synthesis of Sulfonated Carbon Nanocage and Its Performance as Solid Acid Catalyst

A Novel Sulfonated Carbon Composite Solid Acid Catalyst for Biodiesel Synthesis

Template Preparation of Highly Active and Selective Cu–Cr Catalysts with High Surface Area for Glycerol Hydrogenolysis

Facile Preparation of Ionic Liquid Functionalized Magnetic Nano-Solid Acid Catalysts for Acetalization Reaction

An Efficient and Ecofriendly WOx–ZrO2 Solid Acid Catalyst for Classical Mannich Reaction

Zirconium Phosphate with a High Surface Area as a Water-Tolerant Solid Acid

Hydrolysis of Cellulose Selectively into Glucose Over Sulfonated Activated-Carbon Catalyst Under Hydrothermal Conditions

Preparation of a Sulfonated Porous Carbon Catalyst with High Specific Surface Area