NDLI: Partial oxidation of methane to syngas in BaCe0.15Fe0.85O3−δ membrane reactors

Content Provider	Springer Nature Link
Author	Zhu, Xuefeng Wang, HaiHui Cong, You Yang, Weishen
Copyright Year	2006
Abstract	Dense planar Ba0.15Ce0.85FeO3−δ (BCF1585) membrane reactors were investigated to produce syngas from methane. Firstly, the membrane itself catalytic activity to methane was investigated using a blank BCF1585 without any catalysts. Then a LiLaNi/γ-Al2O3 catalyst was packed on the BCF1585 membrane surface to test the synergetic effects of the membrane and catalyst. It was found that the membrane itself has a poor catalytic activity to methane. The main products are CO2 and C2, and methane conversion is low due to the low oxygen permeation flux. However, after the catalyst was packed on the membrane surface, both methane conversion and oxygen permeation flux were greatly improved by the synergetic effect between the membrane and catalyst. Carbon monoxide selectivity reached at 96% with methane conversion of up to 96%. The oxygen permeation flux reached at 3.0 mL/cm2 min at 850 °C for a 1.5 mm disk membrane and can effectively be increased by reducing the thickness of the membranes. After operation for 140 h at 850 °C, the used membrane was examined with SEM and EDXS. The results revealed that the decomposition of the membrane materials could not be avoided under such conditions. Oxygen partial pressure gradient across the membranes is suggested as a critical factor to accelerate the kinetic decomposition of the materials.
Starting Page	179
Ending Page	185
Page Count	7
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	111
Issue Number	3-4
e-ISSN	1572879X
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2006-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	oxygen permeation membrane reactor syngas stability perovskite oxides Physical Chemistry Industrial Chemistry/Chemical Engineering Catalysis Pharmacy
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Novel and Ideal Zirconium-Based Dense Membrane Reactors for Partial Oxidation of Methane to Syngas

Mössbauer Spectra and Catalytic Behaviorof Perovskite-like SrFe0.7Al0.3O3-δ

Methane Partial Oxidation Using A (La0.6Sr0.4)(Ga0.8Mg0.05Co0.15)O3–δ Membrane

Partial Oxidation of Methane into Syngas with Oxygen Permeating Ceramic Membrane Reactors

Catalytic partial “oxidation of methane to syngas” at elevated pressures

Comparison of oxygen permeation through some perovskite membranes synthesized with EDTNAD

Partial oxidation of methane to syngas using NiO‐supported catalysts

Sonochemically Prepared high Dispersed Ru/TiO2 Mesoporous Catalyst for Partial Oxidation of Methane to Syngas

A dual catalyst bed for the autothermal partial oxidation of methane to synthesis gas

Partial oxidation of methane to syngas in BaCe0.15Fe0.85O3−δ membrane reactors

Similar Documents

Novel and Ideal Zirconium-Based Dense Membrane Reactors for Partial Oxidation of Methane to Syngas

Mössbauer Spectra and Catalytic Behaviorof Perovskite-like SrFe0.7Al0.3O3-δ

Methane Partial Oxidation Using A (La0.6Sr0.4)(Ga0.8Mg0.05Co0.15)O3–δ Membrane

Partial Oxidation of Methane into Syngas with Oxygen Permeating Ceramic Membrane Reactors

Catalytic partial “oxidation of methane to syngas” at elevated pressures

Comparison of oxygen permeation through some perovskite membranes synthesized with EDTNAD

Partial oxidation of methane to syngas using NiO‐supported catalysts

Sonochemically Prepared high Dispersed Ru/TiO2 Mesoporous Catalyst for Partial Oxidation of Methane to Syngas

A dual catalyst bed for the autothermal partial oxidation of methane to synthesis gas

Partial oxidation of methane to syngas in BaCe0.15Fe0.85O3−δ membrane reactors