NDLI: Catalytic oxidation of methane over novel Ce–Ni–O mixed oxide catalysts prepared by oxalate gel-coprecipitation

Content Provider	Springer Nature Link
Author	Yisup, Nan Cao, Yong Feng, Wei Liang Dai, Wei Lin Fan, Kang Nian
Copyright Year	2005
Abstract	A novel approach for the synthesis of a new type of binary Ce–Ni–O mixed oxide catalysts is reported. The synthesis method involves the homogeneous gel-coprecipitation of oxalate precursor in alcoholic solution followed by calcinations in air. The results show that the as-prepared samples have high specific surface area and high component dispersion, exhibiting remarkably high activity in the catalytic combustion of methane as compared to the catalysts prepared by conventional coprecipitation techniques. It is suggested that the superior catalytic performance of the oxalate gel-coprecipitated Ce–Ni–O mixed oxide catalysts could be attributed to the generation of highly dispersed NiOx species and the creation of highly active oxygen vacancies as a consequence of an easier incorporation of Ni2+ ions into ceria lattice by the formation of solid solution in the mixed oxide samples.
Starting Page	207
Ending Page	213
Page Count	7
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	99
Issue Number	3-4
e-ISSN	1572879X
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2005-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	catalytic combustion of methane Ce–Ni–O mixed oxide catalyst oxalate gel-coprecipitation oxygen vacancy Physical Chemistry Industrial Chemistry/Chemical Engineering Catalysis Pharmacy
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

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