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| Content Provider | Springer Nature Link |
|---|---|
| Author | Swaminathan, Vikhram V. Zhu, Likun Gurau, Bogdan Masel, Richard I. Shann, Mark A. |
| Copyright Year | 2011 |
| Abstract | An ever increasing demand for packaging more energy on-board to meet the needs of power hungry microsystems is driving the miniaturization of power generators. We report a fully integrated Power MEMS, in the 10-μL size, designed to deliver high energy and power densities. On-board hydrogen production and an efficient control scheme that facilitates integration with a fuel cell membrane electrode assembly are key elements for micro energy conversion. A millimeter-scale reactor produces hydrogen by hydrolysis of CaH2 and LiAlH4, to yield energy densities of the order of 200 Whr/L. A passive microfluidic control scheme, incorporating surface tension to pump water in a microchannel for hydrolysis and microvalve control using hydrogen backpressure, facilitates delivery and regulation and eliminates bulky auxiliaries that consume parasitic power. We tested the ability of this control scheme to improve uniformity of power delivery during long periods of lower demand, with fast switching to mass transport regime on the order of seconds, and realized peak power density of up to 391.85 W/L. Prototypes have been tested for duty periods from 2–48 h, with multiple switching of power demand in order to establish performance across multiple regimes. Critical to the realization of the integrated power MEMS, and its energy and power density, are effects of water transport and byproduct hydrate swelling on hydrogen production in the microreactor. While CaH2 showed superior hydrogen release kinetics that enhances power density, LiAlH4 provided greater energy density due to reduced byproduct expansion that permitted increased hydrogen production. |
| Starting Page | 735 |
| Ending Page | 749 |
| Page Count | 15 |
| File Format | |
| ISSN | 16134982 |
| Journal | Microfluidics and Nanofluidics |
| Volume Number | 12 |
| Issue Number | 5 |
| e-ISSN | 16134990 |
| Language | English |
| Publisher | Springer-Verlag |
| Publisher Date | 2011-12-02 |
| Publisher Place | Berlin, Heidelberg |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Micro fuel cell Microvalve Micro hydrogen generator Hydride MEMS Industrial Chemistry/Chemical Engineering Biomedical Engineering Engineering Fluid Dynamics |
| Content Type | Text |
| Resource Type | Article |
| Subject | Nanoscience and Nanotechnology Materials Chemistry Condensed Matter Physics Electronic, Optical and Magnetic Materials |
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