NDLI: Retention Indices of 55 Solutes Belonging to Eight Monofunctional Groups Homologous Series on 14 Chromatographic Capillary Columns

Content Provider	Springer Nature Link
Author	Santiuste, José M. Lebrón Aguilar, Rosa Quintanilla López, Jesús Eduardo
Copyright Year	2010
Abstract	Retention indices, RI, of 55 solutes belonging to eight chemical monofunctional group series were computed at 373 K from retention factors measurements on 14 capillary columns coated with stationary phases, SP, spanning almost the whole polarity range. RI-values of some of these analytes were validated by comparison with literature values. Positive slope straight lines were obtained for the isothermal RI versus Z plots for the eight chemical functions. For a given series the slope (A) is rather insensitive to RP, while the intercept (FF) clearly increases linearly with increasing RP. For a given stationary phase A does not show any clear trend with increasing solute polarity, while FF increases clearly from the less polar to the most polar series.
Starting Page	511
Ending Page	522
Page Count	12
File Format	PDF
ISSN	00095893
Journal	Chromatographia
Volume Number	72
Issue Number	5-6
e-ISSN	16121112
Language	English
Publisher	Vieweg Verlag
Publisher Date	2010-07-04
Publisher Place	Wiesbaden
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Gas chromatography Retention indices Chemical monofunctional solute series Methylene group and polarity of solutes Measurement Science and Instrumentation Plant Sciences Biochemistry Pharmacy Organic Chemistry Analytical Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Analytical Chemistry Biochemistry Clinical Biochemistry

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