NDLI: Analysis of Solvent–Solvent Interactions in Mixed Isosteric Solvents by Inverse Gas Chromatography

Content Provider	Springer Nature Link
Author	Sreekanth, T. V. M. Reddy, K. S.
Copyright Year	2006
Abstract	The Flory–Huggins interaction parameter, χ 23, characterizing the interaction between solvents in a mixed stationary phase has been calculated using inverse gas chromatography (IGC). The χ 23 parameters for four mixed solvent systems formed by mixing a non-polar branched alkane, 19, 24-dioctadecyldotetracontane (C78), with four different polar solvents are analysed as a function of temperature. Two of the polar solvents are formed by replacing one of the –CH3 groups of C78 by –OH (POH) group and –CN (PCN) group and the other two polar solvents are formed by replacing all the four –CH3 groups of C78 by four –CF3 (TTF) groups and four –OCH3 (TMO) groups. The five solvents have similar structures and nearly the same molar volume and in mixtures, they form regular solutions. For the mixture, C78 + POH, χ 23 was calculated at two compositions and for the remaining three mixtures χ 23 was calculated at equimolar composition. Eight solute probes representing all possible chemical structures and polarity were used under conditions approaching infinite dilution. The effects of temperature, concentration of the mixed solvent and probe solute on χ 23 are presented and discussed. The probe-independent χ 23 values were also calculated by linear regression analysis using the retention data of all the solute probes. In all the mixed solvents considered here the χ 23 values are probe-dependent and decrease with increase of temperature.
Starting Page	325
Ending Page	330
Page Count	6
File Format	PDF
ISSN	00095893
Journal	Chromatographia
Volume Number	65
Issue Number	5-6
e-ISSN	16121112
Language	English
Publisher	Vieweg Verlag
Publisher Date	2007-01-09
Publisher Place	Wiesbaden
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Inverse gas chromatography Flory–Huggins parameter Solvent–solvent interaction Chemical potential Isosteric solvents Measurement Science, Instrumentation Plant Sciences Biochemistry Pharmacy Organic Chemistry Analytical Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Analytical Chemistry Biochemistry Clinical Biochemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Inverse gas chromatography. Relationship between mass activity coefficient and flory-huggins interaction parameter in the examination of petroleum pitches

GC Investigation of the Solubility Parameters of Water-Soluble Homopolymers and Double-Hydrophilic Diblock Copolymers

Examination of Polystyrene by Inverse GC: Part 2. Above Glass Transition Temperature

Solubility parameter determination of cationic surfactants by inverse GC

Selectivity of Several Liquid Phases for the Separation of Pine Terpenes by Gas Chromatography

Examination of polyolefins-organic compounds interactions by inverse gas chromatography

Time separation of adsorption sites on heterogeneous surfaces by inverse gas chromatography

Reversed phase behaviour of high molar mass polystyrenes in acetonitrile with halogenated methane solvent mixtures

Surface Characterization of Sepiolite by Inverse Gas Chromatography

Analysis of Solvent–Solvent Interactions in Mixed Isosteric Solvents by Inverse Gas Chromatography

Similar Documents

Inverse gas chromatography. Relationship between mass activity coefficient and flory-huggins interaction parameter in the examination of petroleum pitches

GC Investigation of the Solubility Parameters of Water-Soluble Homopolymers and Double-Hydrophilic Diblock Copolymers

Examination of Polystyrene by Inverse GC: Part 2. Above Glass Transition Temperature

Solubility parameter determination of cationic surfactants by inverse GC

Selectivity of Several Liquid Phases for the Separation of Pine Terpenes by Gas Chromatography

Examination of polyolefins-organic compounds interactions by inverse gas chromatography

Time separation of adsorption sites on heterogeneous surfaces by inverse gas chromatography

Reversed phase behaviour of high molar mass polystyrenes in acetonitrile with halogenated methane solvent mixtures

Surface Characterization of Sepiolite by Inverse Gas Chromatography

Analysis of Solvent–Solvent Interactions in Mixed Isosteric Solvents by Inverse Gas Chromatography