Please wait, while we are loading the content...
Please wait, while we are loading the content...
| Content Provider | Springer Nature Link |
|---|---|
| Author | Jiang, Zhou ting Xu, Peng Sun, Ting ting |
| Copyright Year | 2012 |
| Abstract | The structural transition of a single polymer chain with chain length of 100, 200 and 300 beads was investigated by parallel tempering MD simulation. Our simulation results can capture the structural change from random coil to orientationally ordered structure with decreasing temperature. The clear transition was observed on the curves of radius of gyration and global orientational order parameter P as the function of temperature, which demonstrated structural formation of a single polymer chain. The linear relationships between three components of square radius of gyration R gx 2 , R gy 2 , R gz 2 and global orientational order P can be obtained under the structurally transformational process. The slope of the linear relationship between x (or y-axis) component R gx 2 (or R gy 2 ) and P is negative, while that of R gz 2 as the function of P is positive. The absolute value of slope is proportional to the chain length. Once the single polymer chain takes the random coil or ordered configuration, the linear relationship is invalid. The conformational change was also analyzed on microscopic scale. The polymer chain can be treated as the construction of rigid stems connecting by flexible loops. The deviation from exponentially decreased behavior of stem length distribution becomes prominent, indicating a stiffening of the chain arises leading to more and more segments ending up in the trans state with decreasing temperature. The stem length N tr is about 21 bonds indicating the polymer chain is ordered with the specific fold length. So, the simulation results, which show the prototype of a liquid-crystalline polymer chain, are helpful to understand the crystallization process of crystalline polymers. |
| Starting Page | 45 |
| Ending Page | 55 |
| Page Count | 11 |
| File Format | |
| ISSN | 02567679 |
| Journal | Chinese Journal of Polymer Science |
| Volume Number | 30 |
| Issue Number | 1 |
| e-ISSN | 14396203 |
| Language | English |
| Publisher | Chinese Chemical Society and Institute of Chemistry, CAS |
| Publisher Date | 2011-12-10 |
| Publisher Place | Heidelberg |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | A polymer chain Structural transition Parallel tempering molecular dynamics Characterization and Evaluation of Materials Polymer Sciences Condensed Matter Physics Industrial Chemistry/Chemical Engineering |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Chemical Engineering Polymers and Plastics |
National Digital Library of India (NDLI) is a virtual repository of learning resources which is not just a repository with search/browse facilities but provides a host of services for the learner community. It is sponsored and mentored by Ministry of Education, Government of India, through its National Mission on Education through Information and Communication Technology (NMEICT). Filtered and federated searching is employed to facilitate focused searching so that learners can find the right resource with least effort and in minimum time. NDLI provides user group-specific services such as Examination Preparatory for School and College students and job aspirants. Services for Researchers and general learners are also provided. NDLI is designed to hold content of any language and provides interface support for 10 most widely used Indian languages. It is built to provide support for all academic levels including researchers and life-long learners, all disciplines, all popular forms of access devices and differently-abled learners. It is designed to enable people to learn and prepare from best practices from all over the world and to facilitate researchers to perform inter-linked exploration from multiple sources. It is developed, operated and maintained from Indian Institute of Technology Kharagpur.
Learn more about this project from here.
NDLI is a conglomeration of freely available or institutionally contributed or donated or publisher managed contents. Almost all these contents are hosted and accessed from respective sources. The responsibility for authenticity, relevance, completeness, accuracy, reliability and suitability of these contents rests with the respective organization and NDLI has no responsibility or liability for these. Every effort is made to keep the NDLI portal up and running smoothly unless there are some unavoidable technical issues.
Ministry of Education, through its National Mission on Education through Information and Communication Technology (NMEICT), has sponsored and funded the National Digital Library of India (NDLI) project.
| Sl. | Authority | Responsibilities | Communication Details |
|---|---|---|---|
| 1 | Ministry of Education (GoI), Department of Higher Education |
Sanctioning Authority | https://www.education.gov.in/ict-initiatives |
| 2 | Indian Institute of Technology Kharagpur | Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project | https://www.iitkgp.ac.in |
| 3 | National Digital Library of India Office, Indian Institute of Technology Kharagpur | The administrative and infrastructural headquarters of the project | Dr. B. Sutradhar bsutra@ndl.gov.in |
| 4 | Project PI / Joint PI | Principal Investigator and Joint Principal Investigators of the project |
Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon |
| 5 | Website/Portal (Helpdesk) | Queries regarding NDLI and its services | support@ndl.gov.in |
| 6 | Contents and Copyright Issues | Queries related to content curation and copyright issues | content@ndl.gov.in |
| 7 | National Digital Library of India Club (NDLI Club) | Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach | clubsupport@ndl.gov.in |
| 8 | Digital Preservation Centre (DPC) | Assistance with digitizing and archiving copyright-free printed books | dpc@ndl.gov.in |
| 9 | IDR Setup or Support | Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops | idr@ndl.gov.in |
|
Loading...
|