NDLI: Dynamical aspects and the role of IVR for the reactivity of noble metal clusters towards molecular oxygen

Content Provider	Springer Nature Link
Author	Mitrić, R. Werner, U. Bürgel, C. Bonačić Koutecký, V.
Copyright Year	2007
Abstract	Here, we present the dynamical aspects and the role of internal energy redistribution (IVR) in the reactivity of noble metal clusters towards O2. We show on the example of Ag3O2 - / Ag3O2 / Ag3O2 + that NeNePo spectroscopy carried out under zero electron kinetic energy (ZEKE) conditions can be a powerful tool to investigate the geometry relaxation and IVR induced by photodetachment in real time. Furthermore, we demonstrate that difference in the reactivity of Ag6 - and Au6 - towards O2 can be attributed to different nature of the IVR process. Dissipative IVR in Ag6 - favors fast complex stabilization, whereas resonant IVR found for Au6 - might be an important factor determining the catalytic activity of Au6 - cluster in the CO oxidation.
Starting Page	201
Ending Page	204
Page Count	4
File Format	PDF
ISSN	14346060
Journal	The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics
Volume Number	43
Issue Number	1-3
e-ISSN	14346079
Language	English
Publisher	EDP Sciences
Publisher Date	2007-05-24
Publisher Place	Les Ulis
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Atoms, Molecules, Clusters and Plasmas Nanotechnology Quantum Physics Quantum Computing, Information and Physics Complexity Solid State Physics and Spectroscopy
Content Type	Text
Resource Type	Article
Subject	Atomic and Molecular Physics, and Optics

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Dynamical aspects and the role of IVR for the reactivity of noble metal clusters towards molecular oxygen