NDLI: Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene

Content Provider	Springer Nature Link
Author	Yue, Ruirui Chen, Shuai Liu, Congcong Lu, Baoyang Xu, Jingkun Wang, Jianmin Liu, Guodong
Copyright Year	2011
Abstract	Poly(1,12-bis(carbazolyl)dodecane-co-thieno[3,2-b]thiophene) (P(2Cz-D-co-TT)), a conducting copolymer was synthesized electrochemically by direct anodic oxidation of 1,12-bis(carbazolyl)dodecane (2Cz-D) and thieno[3,2-b]thiophene (TT) in boron trifluoride diethyl ethrate containing 30% (vol) dichloromethane. As-formed copolymers exhibited high redox activity and reversibility and good conductive properties. The emitting property of as-formed copolymer was different from those of respective homopolymers, and could be tuned by changing the initiate monomer feed ratios. Thermoelectric investigations revealed that the electrical conductivities of as-obtained copolymer films were between 0.1 and 0.3 S cm−1 at ambient temperature, lower than that of polythieno[3,2-b]thiophene (PTT) (0.42 S cm−1) but two orders of magnitude higher than that of poly(1,12-bis(carbazolyl)dodecane) (P2Cz-D) (10−3 S cm−1). The Seebeck coefficients and the power factors of the copolymers were improved with different degrees compared with those of PTT and P2Cz-D. As expected, the thermoelectric performance of PTT and P2Cz-D were both improved through copolymerization, which may be beneficial to the exploration and investigation of novel organic thermoelectric materials.
Starting Page	117
Ending Page	126
Page Count	10
File Format	PDF
ISSN	14328488
Journal	Journal of Solid State Electrochemistry
Volume Number	16
Issue Number	1
e-ISSN	14330768
Language	English
Publisher	Springer-Verlag
Publisher Date	2011-01-20
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Conducting polymers Electrochemical copolymerization Thermoelectric material Polythiophene Polycarbazole Physical Chemistry Characterization and Evaluation of Materials Energy Storage Analytical Chemistry Condensed Matter Physics Electrochemistry
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics Materials Science Electrical and Electronic Engineering Electrochemistry

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