NDLI: Thermodynamic properties of the ternary oxides in the Eu–Ru–O system by using solid-state electrochemical cells

Content Provider	Springer Nature Link
Author	Banerjee, Aparna Prasad, R. Venugopal, V.
Copyright Year	2006
Abstract	The Gibbs free energies of formation of Eu3RuO7(s) and Eu2Ru2O7(s) have been determined using solid-state electrochemical technique employing oxide ion conducting electrolyte. The reversible electromotive force (e.m.f.) of the following solid-state electrochemical cells have been measured: $$Cell{\left( I \right)}:{{\left( - \right)}Pt} \mathord{\left/ {\vphantom {{{\left( - \right)}Pt} {{\left\{ {Eu_{3} RuO_{7} {\left( s \right)} + Eu_{2} O_{3} {\left( s \right)} + Ru{\left( s \right)}} \right\}}}}} \right. -} {{\left\{ {Eu_{3} RuO_{7} {\left( s \right)} + Eu_{2} O_{3} {\left( s \right)} + Ru{\left( s \right)}} \right\}}}//CSZ//O_{2} {{\left( {p{\left( {O_{2} } \right)} = 21.21 kPa} \right)}} \mathord{\left/ {\vphantom {{{\left( {p{\left( {O_{2} } \right)} = 21.21 kPa} \right)}} {Pt{\left( + \right)}}}} \right. -} {Pt{\left( + \right)}}$$ $$Cell{\left( {II} \right)}:{{\left( - \right)}Pt} \mathord{\left/ {\vphantom {{{\left( - \right)}Pt} {{\left\{ {Eu_{3} RuO_{7} {\left( s \right)} + Eu_{2} Ru_{2} O_{7} {\left( s \right)} + Ru{\left( s \right)}} \right\}}}}} \right. -} {{\left\{ {Eu_{3} RuO_{7} {\left( s \right)} + Eu_{2} Ru_{2} O_{7} {\left( s \right)} + Ru{\left( s \right)}} \right\}}}//CSZ//O_{2} {{\left( {p{\left( {O_{2} } \right)} = 21.21 kPa} \right)}} \mathord{\left/ {\vphantom {{{\left( {p{\left( {O_{2} } \right)} = 21.21 kPa} \right)}} {Pt{\left( + \right)}}}} \right. -} {Pt{\left( + \right)}}$$ The Gibbs free energies of formation of Eu3RuO7(s) and Eu2Ru2O7(s) from elements in their standard state, calculated by the least squares regression analysis of the data obtained in the present study, can be given, respectively, by: $$\left\{ {\Delta _{f} G^{o} } \right.\left. {{{\left( {Eu_{3} RuO_{7} , s} \right)}} \mathord{\left/ {\vphantom {{{\left( {Eu_{3} RuO_{7} , s} \right)}} {{\left( {kJ \cdot mol^{{ - 1}} } \right)} \pm 2.5}}} \right. -} {{\left( {kJ \cdot mol^{{ - 1}} } \right)} \pm 2.5}} \right) = - 2,785.2 + 0.567 \cdot {\left( {T \mathord{\left/ {\vphantom {T K}} \right. -} K} \right)}; {\left( {{922.5 \leqslant T} \mathord{\left/ {\vphantom {{922.5 \leqslant T} {K \leqslant 1194.9}}} \right. -} {K \leqslant 1194.9}} \right)}.$$ $$\left\{ {\Delta _{f} G^{o} } \right.\left. {{{\left( {Eu_{3} Ru_{2} O_{7} , s} \right)}} \mathord{\left/ {\vphantom {{{\left( {Eu_{3} Ru_{2} O_{7} , s} \right)}} {{\left( {kJ \cdot mol^{{ - 1}} } \right)} \pm 2.9}}} \right. -} {{\left( {kJ \cdot mol^{{ - 1}} } \right)} \pm 2.9}} \right) = - 2,256.6 + 0.579 \cdot {\left( {T \mathord{\left/ {\vphantom {T K}} \right. -} K} \right)}; {\left( {{995.3 \leqslant T} \mathord{\left/ {\vphantom {{995.3 \leqslant T} {K \leqslant 1260.6}}} \right. -} {K \leqslant 1260.6}} \right)}.$$ The uncertainty estimates for Δf G o(T) include the standard deviation in e.m.f. and uncertainty in the data taken from the literature.
Starting Page	291
Ending Page	295
Page Count	5
File Format	PDF
ISSN	14328488
Journal	Journal of Solid State Electrochemistry
Volume Number	11
Issue Number	2
e-ISSN	14330768
Language	English
Publisher	Springer-Verlag
Publisher Date	2006-04-12
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	System Eu–Ru–O Europium ruthenates Solid-state electrochemical technique Gibbs free energy of formation Electronic and Computer Engineering Condensed Matter Characterization and Evaluation Materials Industrial Chemistry/Chemical Engineering Analytical Chemistry Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics Materials Science Electrical and Electronic Engineering Electrochemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

System Zn–Rh–O: heat capacity and Gibbs free energy of formation using differential scanning calorimeter and electrochemical cell

Determination of thermodynamic properties of YRhO3(s) by solid-state electrochemical cell and differential scanning calorimeter

Thermodynamic properties of the pyrochlore Gd2Ru2O7(s) by solid oxide electrochemical cell

Electrochemical study of the thermodynamic properties of matildite (β-AgBiS2) in different temperature and compositional ranges

Electrochemical determination of thermodynamic properties of DyRhO3 and phase relations in the system Dy-Rh-O

System Dy-Fe-O: Thermodynamic Properties Of Ternary Oxides Using Calvet Calorimetry And Solid-state Electrochemical Cell

Oxygen stoichiometry, unit cell volume, and thermodynamic quantities of perovskite-type oxides

Thermodynamic aspects of capillarity and electrocapillarity of solid interfaces

Formation of stable phases of the Li–Mn–Co oxide system at 800 °C under ambient oxygen pressure

Thermodynamic properties of the ternary oxides in the Eu–Ru–O system by using solid-state electrochemical cells

Similar Documents

System Zn–Rh–O: heat capacity and Gibbs free energy of formation using differential scanning calorimeter and electrochemical cell

Determination of thermodynamic properties of YRhO3(s) by solid-state electrochemical cell and differential scanning calorimeter

Thermodynamic properties of the pyrochlore Gd2Ru2O7(s) by solid oxide electrochemical cell

Electrochemical study of the thermodynamic properties of matildite (β-AgBiS2) in different temperature and compositional ranges

Electrochemical determination of thermodynamic properties of DyRhO3 and phase relations in the system Dy-Rh-O

System Dy-Fe-O: Thermodynamic Properties Of Ternary Oxides Using Calvet Calorimetry And Solid-state Electrochemical Cell

Oxygen stoichiometry, unit cell volume, and thermodynamic quantities of perovskite-type oxides

Thermodynamic aspects of capillarity and electrocapillarity of solid interfaces

Formation of stable phases of the Li–Mn–Co oxide system at 800 °C under ambient oxygen pressure

Thermodynamic properties of the ternary oxides in the Eu–Ru–O system by using solid-state electrochemical cells