NDLI: Electrocatalytic oxidation of methanol on NiZnsalenA modified glassy carbon electrode

Content Provider	Springer Nature Link
Author	Wang, Wenyang Li, Ruifeng Liu, Lu Zhang, Rong Wang, Baocheng
Copyright Year	2015
Abstract	Nickel and zinc salen complexes were simultaneously encapsulated in the supercages of the mesoporous zeolite A by using the flexible ligand method. This heterogeneous catalyst NiZnsalenA was characterized by X-ray diffraction, infrared spectroscopy, diffuse reflectance UV-vis spectroscopy, elemental analysis, and N2 adsorption/desorption experiments. The techniques of cyclic voltammetry (CV) and chronoamperometry (CA) were employed to investigate the electrochemical behavior and electrocatalytic activity toward the oxidation of methanol on NiZnsalenA glassy carbon electrode (GCE) in 0.1-M NaOH solution. The CV results presented a pair of redox peaks associated with the Ni2+(salen)(OH)2/Ni3+(salen)O(OH) redox couple. NiZnsalenA also showed the superior electrocatalytic activity to the oxidation of methanol than pure Ni-modified electrode, mainly due to a synergetic effect in NiZnsalenA. This synergetic effect may originate from the interaction of Ni(salen) and Zn(salen) and/or the formation of dinuclear salen complexes via the lattice oxygen of the zeolitic host. The effects of the scan rate, methanol concentration, and OH− concentration on methanol oxidation are investigated, and a possible mechanism is proposed that the oxidation of methanol is done by reaction with Ni3+(salen)O(OH) and also direct electrooxidation reaction. The kinetic parameters such as the electron transfer coefficient α and the rate constant k s of the electrode reaction were estimated to be 0.39 and 1.59 s−1, respectively. In both the CA and CC studies, the process of methanol oxidation followed a Cottrellian behavior, and the diffusion coefficients D CA and D CC of methanol represented the similar tendency, where an initial sharp drop was terminated to a very slow change as the concentration of methanol was approaching 0.7 M. The catalytic rate constant k cat increased rapidly until the concentration of methanol was increased above 0.7 M, and then the values of k cat remained almost constant.
Starting Page	2001
Ending Page	2012
Page Count	12
File Format	PDF
ISSN	14328488
Journal	Journal of Solid State Electrochemistry
Volume Number	19
Issue Number	7
e-ISSN	14330768
Language	English
Publisher	Springer Berlin Heidelberg
Publisher Date	2015-03-10
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Methanol Electrocatalysis (NiZn, Ni) salen complex Zeolite-encapsulation modified electrode Direct methanol fuel cell Physical Chemistry Electrochemistry Energy Storage Characterization and Evaluation of Materials Analytical Chemistry Condensed Matter Physics
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics Materials Science Electrical and Electronic Engineering Electrochemistry

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