NDLI: Electrochemistry of hydrogen-bonding systems

Content Provider	Springer Nature Link
Author	Moon, Kwangyul Philip, Ivy Sun, Hao Kaifer, Angel E.
Copyright Year	2007
Abstract	Hydrogen bonding is one of the most important intermolecular forces in molecular self-assembly or non-covalent synthesis. It is now possible to prepare rather large supramolecular assemblies (>1,000 Da) held together by hydrogen bonds between their molecular building blocks. From the standpoint of electrochemistry, this opens up interesting research avenues. This manuscript reviews recent results-mostly from the authors’ own group—on the electrochemistry of systems in which hydrogen bonding plays a crucial role. First, we explore the encapsulation of redox-active centers inside large hydrogen-bonded assemblies and its effects on the kinetics and thermodynamics of the electron transfer reactions of the encapsulated center. Second, we survey the use of electrochemistry to modulate the strength of hydrogen bonding between complementary partners. In this regard, the association and dissociation of dimeric calixarene molecular capsules can be fully controlled by the oxidation state of ferrocenyl centers located nearby the hydrogen-bonding sites. Finally, we also present very recent and intriguing results on the strong electronic coupling between two equivalent ferrocenyl centers held together by four hydrogen bonds in a non-covalent dimer.
Starting Page	1635
Ending Page	1641
Page Count	7
File Format	PDF
ISSN	14328488
Journal	Journal of Solid State Electrochemistry
Volume Number	11
Issue Number	12
e-ISSN	14330768
Language	English
Publisher	Springer-Verlag
Publisher Date	2007-04-28
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Hydrogen bonding Electrochemistry Voltammetry Self-assembly Electronic and Computer Engineering Condensed Matter Characterization and Evaluation of Materials Industrial Chemistry/Chemical Engineering Analytical Chemistry Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics Materials Science Electrical and Electronic Engineering Electrochemistry

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