NDLI: Electrochemical synthesis and characterization of poly(3,4-ethylenedioxythiophene) in ionic liquids with bulky organic anions

Content Provider	Springer Nature Link
Author	Danielsson, Petter Bobacka, Johan Ivaska, Ari
Copyright Year	2004
Abstract	The electrochemistry of poly(3,4-ethylenedioxythiophene) (PEDOT) was studied in two ionic liquids with bulky organic anions, i.e., 1-butyl-3-methylimidazolium (BMIM) diethylene glycol monomethyl ether sulfate (MDEGSO4) and BMIM octyl sulfate (OctSO4). BMIM-MDEGSO4 is a liquid, while BMIM-OctSO4 is in solid form at room temperature. Electrosynthesis of PEDOT in BMIM-MDEGSO4 with an EDOT concentration of 0.1 M and in BMIM-MDEGSO4/EDOT 1/1 (w/w) solution resulted in no polymer at all or a very limited amount of polymer on the electrode surface, as determined by cyclic voltammetry in 0.1 M KCl(aq) solution. In contrast, electrosynthesis of PEDOT in BMIM-OctSO4/EDOT 1/1 (w/w) resulted in a high yield of electroactive material on the electrode surface. Furthermore, electrosynthesis of PEDOT in ionic liquid–water solution (Cionic liquid=1.5 M) containing 0.1 M EDOT was also found to give a relatively high yield of electroactive material on the electrode surface, both for 1.5 M BMIM-MDEGSO4(aq) and 1.5 M BMIM-OctSO4(aq). The PEDOT electrodes showed an anionic potentiometric response in 10−5–10−1 M KCl(aq) solution, indicating a predominant anion transfer at the polymer–solution interface despite the relatively bulky anions (MDEGSO4− or OctSO4−) incorporated as counterions in PEDOT during electropolymerization. On the basis of electrochemical impedance spectroscopy, the charge (ion) transport properties of the polymer film were strongly influenced by the water content of the ionic liquid (Cionic liquid=0.05–2.0 M).
Starting Page	809
Ending Page	817
Page Count	9
File Format	PDF
ISSN	14328488
Journal	Journal of Solid State Electrochemistry
Volume Number	8
Issue Number	10
e-ISSN	14330768
Language	English
Publisher	Springer-Verlag
Publisher Date	2004-08-12
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Conducting polymer Ionic liquid Cyclic voltammetry Potentiometry Electrochemical impedance spectroscopy
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics Materials Science Electrical and Electronic Engineering Electrochemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Redox capacitance of poly-3,4-ethylenedioxythiophene studied by cyclic voltammetry and faradaic impedance spectroscopy

Electrochemical properties of composite films based on poly-3,4-ethylenedioxythiophene with inclusions of metallic palladium

Polyaniline- and poly(ethylenedioxythiophene)-cellulose nanocomposite electrodes for supercapacitors

Spectroelectrochemical study of poly-3,4-ethylenedioxythiophene films in the presence of different supporting electrolytes

Preparation and characterization of a rechargeable battery based on poly-(3,4-ethylenedioxythiophene) and aluminum in ionic liquids

Synthesis and electrochemical properties of composite films based on poly-3,4-ethylenedioxythiophene with inclusions of silver particles

Synthesis and electrochemical properties of composite materials based on poly-3,4-ethylenedioxythiophene with manganese dioxide inclusions

Electroless deposition of gold into poly-3,4-ethylenedioxythiophene films and their characterization performed in chloride-containing solutions

Gold electroless deposition into poly-3,4-ethylenedioxythiophene films

Electrochemical synthesis and characterization of poly(3,4-ethylenedioxythiophene) in ionic liquids with bulky organic anions

Similar Documents

Redox capacitance of poly-3,4-ethylenedioxythiophene studied by cyclic voltammetry and faradaic impedance spectroscopy

Electrochemical properties of composite films based on poly-3,4-ethylenedioxythiophene with inclusions of metallic palladium

Polyaniline- and poly(ethylenedioxythiophene)-cellulose nanocomposite electrodes for supercapacitors

Spectroelectrochemical study of poly-3,4-ethylenedioxythiophene films in the presence of different supporting electrolytes

Preparation and characterization of a rechargeable battery based on poly-(3,4-ethylenedioxythiophene) and aluminum in ionic liquids

Synthesis and electrochemical properties of composite films based on poly-3,4-ethylenedioxythiophene with inclusions of silver particles

Synthesis and electrochemical properties of composite materials based on poly-3,4-ethylenedioxythiophene with manganese dioxide inclusions

Electroless deposition of gold into poly-3,4-ethylenedioxythiophene films and their characterization performed in chloride-containing solutions

Gold electroless deposition into poly-3,4-ethylenedioxythiophene films

Electrochemical synthesis and characterization of poly(3,4-ethylenedioxythiophene) in ionic liquids with bulky organic anions