NDLI: Synthesis, crystal structure, and characterization of a new non-centrosymmetric organic–inorganic hybrid material: [C6H16N2]2(BiBr6)NO3

Content Provider	Springer Nature Link
Author	Essid, Manel Roisnel, Thierry Rzaigui, Mohamed Marouani, Houda
Copyright Year	2015
Abstract	A novel organic–inorganic hybrid material, [C6H16N2]2(BiBr6)NO3, was synthesized, and its structure was determined by means of single crystal X-ray diffraction studies at room temperature in the non-centrosymmetric orthorhombic space group P21212 with the following parameters: a = 17.629(5) Å, b = 20.279(5) Å, c = 7.319(5) Å, and Z = 4. The crystal lattice is composed of discrete hexabromobismuthates and nitrate anions surrounded by trans-2,5-dimethylpiperazine-1,4-diium cations linked via simple and bifurcated N–H···Br(O) and weak C–H···Br(O) hydrogen bonds to form three-dimensional network. The vibrational spectrum has been measured at room temperature by FT-IR spectroscopy (4000–400 cm−1) on polycrystalline samples, shows the presence of organic cation and nitrate anion. The number of 13C CP-MAS NMR lines is in full agreement with the crystallographic data.
Starting Page	1959
Ending Page	1965
Page Count	7
File Format	PDF
ISSN	00269247
Journal	Monatshefte für Chemie - Chemical Monthly
Volume Number	146
Issue Number	12
e-ISSN	14344475
Language	English
Publisher	Springer Vienna
Publisher Date	2015-05-21
Publisher Place	Vienna
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Crystal structure Hydrogen bonds IR spectroscopy NMR spectroscopy Chemistry/Food Science Organic Chemistry Inorganic Chemistry Analytical Chemistry Physical Chemistry Theoretical and Computational Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Synthesis, spectroscopic characterization, and X-ray structure analysis of bis(2-amino-4-methylpyrimidin-1-ium) chloride tetrachloroantimonate(III) monohydrate [C5H8N3]2ClSbCl4·H2O

Very strong centrosymmetric [O...H...O]$^{+}$ and asymmetric [O-H...O]$^{+}$ hydrogen bonds in a new POM-Based hybrid material

Synthesis, crystal structure, spectral, dielectric characteristics and conduction mechanism of two novel carboxylates of 1-benzhydrylpiperazine

Synthesis and Physico-chemical studies of a new non-centrosymmetric organic-inorganic hybrid material: [2,3-(CH$_{3}$)$_{2}$C$_{6}$H$_{3}$NH$_{3}$]$_{4}$ BiBr$_{6}$NO$_{3}$.2H$_{2}$O

Synthesis, characterization, and crystal structural study of the iron(II) 4,4′-bithiazole complex [Fe(C6H4N2S2)3]2+(NO3 −)2

Synthesis, structure, and tuberculostatic activity of dimethyl benzoylcarbonohydrazonodithioates

Synthesis, characterization, crystal structure, and DNA interaction of tin complexes containing pyridyl ligands

Preparation, spectroscopic characterization, and crystal structure of a mixed-ligand silver(I) complex with 1,2,4-triazole-based Schiff base and triphenylphosphine

The first alkali metal hydroxide-ammoniate, cesium hydroxide-ammoniate (1:1), CsOH·NH3, synthesis and crystal structure

Synthesis, crystal structure, and characterization of a new non-centrosymmetric organic–inorganic hybrid material: [C6H16N2]2(BiBr6)NO3

Similar Documents

Synthesis, spectroscopic characterization, and X-ray structure analysis of bis(2-amino-4-methylpyrimidin-1-ium) chloride tetrachloroantimonate(III) monohydrate [C5H8N3]2ClSbCl4·H2O

Very strong centrosymmetric [O...H...O]$^{+}$ and asymmetric [O-H...O]$^{+}$ hydrogen bonds in a new POM-Based hybrid material

Synthesis, crystal structure, spectral, dielectric characteristics and conduction mechanism of two novel carboxylates of 1-benzhydrylpiperazine

Synthesis and Physico-chemical studies of a new non-centrosymmetric organic-inorganic hybrid material: [2,3-(CH$_{3}$)$_{2}$C$_{6}$H$_{3}$NH$_{3}$]$_{4}$ BiBr$_{6}$NO$_{3}$.2H$_{2}$O

Synthesis, characterization, and crystal structural study of the iron(II) 4,4′-bithiazole complex [Fe(C6H4N2S2)3]2+(NO3 −)2

Synthesis, structure, and tuberculostatic activity of dimethyl benzoylcarbonohydrazonodithioates

Synthesis, characterization, crystal structure, and DNA interaction of tin complexes containing pyridyl ligands

Preparation, spectroscopic characterization, and crystal structure of a mixed-ligand silver(I) complex with 1,2,4-triazole-based Schiff base and triphenylphosphine

The first alkali metal hydroxide-ammoniate, cesium hydroxide-ammoniate (1:1), CsOH·NH3, synthesis and crystal structure

Synthesis, crystal structure, and characterization of a new non-centrosymmetric organic–inorganic hybrid material: [C6H16N2]2(BiBr6)NO3