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| Content Provider | Springer Nature Link |
|---|---|
| Author | Nieszporek, Jolanta |
| Copyright Year | 2010 |
| Abstract | A two-step Zn2+ ion reduction was estimated at the dropping mercury electrode in 2, 3, and 4 mol dm−3 NaClO4 with the addition of tetramethylthiourea using an impedance method at wide potential and frequency ranges. With increasing tetramethylthiourea and NaClO4 concentrations the $$ k_{{{\text{s}}_{ 1} }}^{t} $$ and $$ k_{{{\text{s}}_{ 2} }}^{t} $$ values increased, achieving their maximum values at the highest concentrations of tetramethylthiourea in 3 and 4 mol dm−3 NaClO4 solutions. The catalytic effect of tetramethylthiourea at its lowest employed concentration increased with increasing NaClO4 concentration. |
| Starting Page | 521 |
| Ending Page | 527 |
| Page Count | 7 |
| File Format | |
| ISSN | 00269247 |
| Journal | Monatshefte für Chemie - Chemical Monthly |
| Volume Number | 141 |
| Issue Number | 5 |
| e-ISSN | 14344475 |
| Language | English |
| Publisher | Springer Vienna |
| Publisher Date | 2010-05-04 |
| Publisher Place | Vienna |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Electroreduction of Zn2+ ions Tetramethylthiourea Catalytic activity True rate constants Theoretical and Computational Chemistry Physical Chemistry Analytical Chemistry Inorganic Chemistry Organic Chemistry Chemistry/Food Science |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry |
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