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| Content Provider | Springer Nature Link |
|---|---|
| Author | Mandal, Mrinmay Oppelt, Kerstin List, Manuela Teasdale, Ian Chakraborty, Debashis Monkowius, Uwe |
| Copyright Year | 2016 |
| Abstract | Four new copper complexes based on bidentate imino phenoxide ligands were synthesized and characterized by IR, UV–Vis spectroscopy, ESI mass spectrometry, single crystal X-ray diffraction, and electrochemistry. The crystal structures revealed that the copper(II) atoms are surrounded by phenolate oxygen and imine nitrogen atoms of two ligands in a distorted square-planar geometry. The existence of ligand-centered, as well as Cu(II)-centered quasi-reversible and reversible redox reactions are observed in the cyclic voltammetry experiments of all the complexes. All complexes are able to catalyze the ring-opening polymerization of rac-lactide yielding polymers with moderate molecular weights and moderately broad molecular weight distributions. |
| Starting Page | 1883 |
| Ending Page | 1892 |
| Page Count | 10 |
| File Format | |
| ISSN | 00269247 |
| Journal | Monatshefte für Chemie - Chemical Monthly |
| Volume Number | 147 |
| Issue Number | 11 |
| e-ISSN | 14344475 |
| Language | English |
| Publisher | Springer Vienna |
| Publisher Date | 2016-09-05 |
| Publisher Place | Vienna |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Imino phenoxide Copper Crystal structure ROP rac-Lactide Cyclic voltammetry Poly(lactic acid) Chemistry/Food Science Organic Chemistry Inorganic Chemistry Analytical Chemistry Physical Chemistry Theoretical and Computational Chemistry |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry |
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