NDLI: Determination of Rare Earth Elements in Acid Mine Drainage by Inductively Coupled Plasma Mass Spectrometry

Content Provider	Springer Nature Link
Author	Merten, Dirk Büchel, Georg
Copyright Year	2004
Abstract	A method was developed for the direct determination of 14 naturally occuring rare earth elements (REE, La–Lu) by means of inductively coupled plasma mass spectrometry in seepage waters caused by acid mine drainage. The analytical procedure includes the additional determination of oxide and hydroxide formation by Ba and REE. The determined polyatomic ion formation can be used to correct spectral interferences of oxides and hydroxides of Ba and the light REE on middle and heavy REE. The total REE content in the acidic seepage waters investigated is up to 220 µg L−1. The concentration of the REE normalized to Post Archean Australian Shale (PAAS) is shown, and fractionation of the REE is discussed. The PAAS-normalized REE-patterns feature an enrichment of middle and heavy REE as opposed to the light ones. For one seepage water sampled over a period of about half a year, the REE patterns show very high reproducibility. The accuracy of the method was demonstrated by the analysis of two water samples containing certified concentrations of REE.
Starting Page	163
Ending Page	170
Page Count	8
File Format	PDF
ISSN	00263672
Journal	Microchimica Acta
Volume Number	148
Issue Number	3-4
e-ISSN	14365073
Language	English
Publisher	Springer-Verlag
Publisher Date	2004-11-02
Publisher Place	Vienna
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Analytical Chemistry Inorganic Chemistry Physical Chemistry Characterization and Evaluation Materials Monitoring/Environmental Analysis/Environmental Ecotoxicology
Content Type	Text
Resource Type	Article
Subject	Analytical Chemistry

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