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| Content Provider | Springer Nature Link |
|---|---|
| Author | Aird, Hannah M. Boudreau, Alan E. |
| Copyright Year | 2013 |
| Abstract | High-temperature carbonate minerals have been observed in association with sulfide minerals below the platiniferous Johns-Manville (J-M) reef of the Stillwater Complex in a stratigraphic section that has been previously shown to be characterized by unusually Cl-rich apatite. The carbonate assemblage consists of dolomite with exsolved calcite in contact with sulfide minerals: chalcopyrite and pyrrhotite in the Peridotite Zone; and pyrrhotite with pentlandite, pyrite and chalcopyrite in Gabbronorite Zone I of the Lower Banded Series. A reaction rim surrounds the carbonate–sulfide assemblages, showing an alteration of the host orthopyroxene to a more calcium-enriched, Fe-depleted pyroxene. The calcite–dolomite geothermometer yields a minimum formation temperature as high as 950 °C for the unmixed assemblages. Iron and manganese concentrations exceed the range seen in carbonatite and mantle xenolith carbonates and are distinctly different from the nearly pure end-member carbonates associated with greenschist-grade (and lower) assemblages (e.g., carbonate veins in serpentinite) that occur locally throughout the complex. The association of high-temperature carbonates with sulfides beneath the J-M reef supports the hydromagmatic theory which involves a late-stage chloride–carbonate fluid percolating upwards, dissolving PGE and sulfides and redepositing them at a higher stratigraphic level. Characterization of the processes which form strategically important metal deposits, such as the J-M reef of the Stillwater Complex and the analogous Merensky reef of the Bushveld Complex in South Africa, could potentially lead to better exploration models and, more broadly, a deeper understanding of the cooling and compositional evolution of large bodies of ultramafic and mafic magma and of carbonatites, on both a local and a regional scale. |
| Starting Page | 1143 |
| Ending Page | 1160 |
| Page Count | 18 |
| File Format | |
| ISSN | 00107999 |
| Journal | Contributions to Mineralogy and Petrology |
| Volume Number | 166 |
| Issue Number | 4 |
| e-ISSN | 14320967 |
| Language | English |
| Publisher | Springer Berlin Heidelberg |
| Publisher Date | 2013-07-05 |
| Publisher Place | Berlin/Heidelberg |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Igneous carbonates Igneous fluids Stillwater Complex Geology Mineral Resources Mineralogy |
| Content Type | Text |
| Resource Type | Article |
| Subject | Geochemistry and Petrology Geophysics |
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