NDLI: A model filler network in nanocomposites prepared by in situ silica filling and peroxide cross-linking in natural rubber latex

Content Provider	Springer Nature Link
Author	Tohsan, Atitaya Kishi, Ryota Ikeda, Yuko
Copyright Year	2015
Abstract	Preparation and characteristics of model filler networks in nanocomposites are reported for development of rubber science. The nanocomposites were prepared via a sol–gel reaction in natural rubber (NR) latex using tetraethoxysilane followed by a peroxide cross-linking reaction in the liquid state employing a casting method. The filler network structure was formed in the NR matrix, even though the silica content was only 10 and 17 parts per one hundred rubber by weight. One of the important factors for the formation of the filler network was utilization of rubber particles in the latex as a template. Dynamic mechanical analysis revealed the significant characteristics of the filler network of silica particles in the rubber matrix: Higher and longer plateau regions of storage modulus and dissipation loss modulus in the low frequency region were observed in the in situ silica-filled nanocomposites compared with conventionally prepared nanocomposites. This was mainly ascribed to a strong filler–filler interaction.
Starting Page	2083
Ending Page	2093
Page Count	11
File Format	PDF
ISSN	0303402X
Journal	Colloid and Polymer Science
Volume Number	293
Issue Number	7
e-ISSN	14351536
Language	English
Publisher	Springer Berlin Heidelberg
Publisher Date	2015-04-28
Publisher Place	Berlin/Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Natural rubber latex In situ silica Filler network Peroxide cross-linking Dynamic mechanical properties Polymer Sciences Soft and Granular Matter, Complex Fluids and Microfluidics Characterization and Evaluation of Materials Physical Chemistry Food Science Nanotechnology and Microengineering
Content Type	Text
Resource Type	Article
Subject	Colloid and Surface Chemistry Materials Chemistry Physical and Theoretical Chemistry Polymers and Plastics

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