NDLI: Spherical and core-shell fluorinated polyacrylate latex particles: preparation and characterization

Content Provider	Springer Nature Link
Author	Yang, Wei Zhu, Liqun Chen, Yichi
Copyright Year	2015
Abstract	Fluorinated polyacrylate particles with spherical (SP) and core-shell (CS) structures have been prepared via emulsion polymerization. Morphologies of SP and CS latex particles were observed by transmission electron microscope (TEM). The copolymer and the film were characterized by Fourier transform infrared spectroscopy (FT-IR), 19F NMR, atomic force microscope (AFM), X-ray photoelectron spectroscopy (XPS), and thermogravimetry (TG-DSC) analyses. Fluorinated components in the copolymer were found to aggregate at the film surface, and the core-shell structure of latex particles contributes to occurrence of phase separation at the film surface. The film prepared from core-shell latex particles exhibits more satisfied water repellency than that obtained from spherical latex particles. Fluorine components at SP and CS film surfaces present significantly different aggregation behaviors.
Starting Page	2349
Ending Page	2357
Page Count	9
File Format	PDF
ISSN	0303402X
Journal	Colloid and Polymer Science
Volume Number	293
Issue Number	8
e-ISSN	14351536
Language	English
Publisher	Springer Berlin Heidelberg
Publisher Date	2015-05-26
Publisher Place	Berlin/Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Fluorinated polyacrylate Core-shell structure Phase separation Surface property Polymer Sciences Soft and Granular Matter, Complex Fluids and Microfluidics Characterization and Evaluation of Materials Physical Chemistry Food Science Nanotechnology and Microengineering
Content Type	Text
Resource Type	Article
Subject	Colloid and Surface Chemistry Materials Chemistry Physical and Theoretical Chemistry Polymers and Plastics

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