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| Content Provider | Springer Nature Link |
|---|---|
| Author | Fu, Chaopeng Zhou, Haihui Wu, Huimin Chen, Jinhua Kuang, Yafei |
| Copyright Year | 2008 |
| Abstract | The nonaqueous ionic liquid (IL) microemulsions composed of 1-butyl-3-methylimidazolium tetrafluoroborate, Triton X-100, and toluene were prepared and the electrochemical properties of the nonaqueous IL microemulsions were investigated in this paper. It is shown that characteristics of the nonaqueous IL microemulsions such as electrical conductivity, electrochemical window, and solubility are good, which indicate that the nonaqueous IL microemulsions can be used as electrolyte for electrochemical research. The electrochemical properties of the nonaqueous IL microemulsions were researched by cyclic voltammetry (CV) and electrochemical impedance spectroscopy methods using potassium ferricyanide as electroactive probe. It was found that the reversibility was better and the peak current densities of CV were higher for the [Fe(CN)6]3−/[Fe(CN)6]4− electrode reaction in the nonaqueous IL microemulsions than those in IL. However, the electrochemical behavior of the probe in the nonaqueous IL microemulsions with different microenvironments (oil-in-IL, IL-in-oil, and bicontinuous) was different. The electrochemical property of the probe in the oil-in-IL microemulsion was the best, which was studied in detail. |
| Starting Page | 1499 |
| Ending Page | 1504 |
| Page Count | 6 |
| File Format | |
| ISSN | 0303402X |
| Journal | Colloid and Polymer Science |
| Volume Number | 286 |
| Issue Number | 13 |
| e-ISSN | 14351536 |
| Language | English |
| Publisher | Springer-Verlag |
| Publisher Date | 2008-09-13 |
| Publisher Place | Berlin/Heidelberg |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Nonaqueous ionic liquid microemulsions Potassium ferricyanid Cyclic voltammetry Electrochemical properties Food Science Physical Chemistry Characterization and Evaluation of Materials Soft Matter, Complex Fluids Polymer Sciences |
| Content Type | Text |
| Resource Type | Article |
| Subject | Colloid and Surface Chemistry Materials Chemistry Physical and Theoretical Chemistry Polymers and Plastics |
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