NDLI: Dissipative crystallization of poly-d-lysine hydrobromide, poly-l-lysine hydrobromide, and their low-molecular-weight analogs

Content Provider	Springer Nature Link
Author	Okubo, Tsuneo Okamoto, Junichi Tsuchida, Akira
Copyright Year	2010
Abstract	Drying dissipative structures of aqueous solutions of poly-d-lysine hydrobromide, poly-l-lysine hydrobromide, and their low-molecular-weight analogs were studied on a cover glass, a watch glass, and a Petri glass dish. Size of the broad rings, one of the typical macroscopic patterns, decreased as the solute concentration decreased. Microscopic drying crystal patterns of polylysine hydrobromides and their low-molecular-weight analogs, i.e., d-, l-, and dl-lysine hydrochloride changed as a function of the distance from the film center, which is one of the typical features of dissipative crystallization. Macroscopic and microscopic drying patterns were quite similar to each other irrespective of their stereospecificity. The crystal patterns of the mixtures of poly-d-lysine hydrobromide and poly-l-lysine hydrobromide were also similar to those of the corresponding single-component polymers. The stereospecific effects were not observed in this work.
Starting Page	981
Ending Page	989
Page Count	9
File Format	PDF
ISSN	0303402X
Journal	Colloid and Polymer Science
Volume Number	288
Issue Number	9
e-ISSN	14351536
Language	English
Publisher	Springer-Verlag
Publisher Date	2010-04-27
Publisher Place	Berlin/Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Poly-d-lysine hydrobromide Poly-l-lysine hydrobromide Dissipative crystallization Dissipative structure Drying pattern Optical isomer Food Science Physical Chemistry Characterization and Evaluation of Materials Soft and Granular Matter, Complex Fluids and Microfluidics Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Colloid and Surface Chemistry Materials Chemistry Physical and Theoretical Chemistry Polymers and Plastics

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