NDLI: Research on association between multi-sticker amphiphilic polymer and water-soluble β-cyclodextrin polymer

Content Provider	Springer Nature Link
Author	Kang, Wanli Ji, Yanfeng Xu, Bin Hu, Leilei Meng, Lingwei Fan, Haiming Bai, Baojun
Copyright Year	2013
Abstract	The host cyclodextrin polymer-P(AM/A-β-CD/NaA) is prepared by redox free-radical copolymerization. Additionally, the multi-sticker amphiphilic polymer-P(AM/BHAM/NaA) as a guest polymer is synthesized using micellar polymerization. The copolymer structures are characterized by 1H NMR. Subsequently, all the polymers and inclusion complexes are evaluated in terms of apparent viscosity, optical absorption spectra and rheological property. The results indicate that the inclusion association between the cyclodextrin group (CD) and multi-sticker hydrophobic monomer (BHAM) is in accordance with ternary interaction (CD/BHAM = 2:1). Because of the inclusion association between the host and guest polymers, the solution of inclusion complex has much higher viscoelasticity even under the low amphiphilic polymer concentration. When the molar ratio of CD to BHAM is 1:1, the critical aggregation concentration (CAC) of the inclusion complex solution still remains. Furthermore, above the CAC, two types of associations, inclusion association and inter-molecular hydrophobic association, can occur in the complex solution and these interactions were also verified by fluorescence spectroscopy and atomic force microscopy (AFM). In this paper, the inclusion rule of cyclodextrin polymer with the multi-sticker amphiphilic polymer is discussed, and the rule of the enhanced solution viscosity is further explored.
Starting Page	895
Ending Page	903
Page Count	9
File Format	PDF
ISSN	0303402X
Journal	Colloid and Polymer Science
Volume Number	292
Issue Number	4
e-ISSN	14351536
Language	English
Publisher	Springer Berlin Heidelberg
Publisher Date	2013-12-07
Publisher Place	Berlin/Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Cyclodextrin polymer Multi-sticker amphiphilic polymer Inclusion association Apparent viscosity Polymer Sciences Soft and Granular Matter, Complex Fluids and Microfluidics Characterization and Evaluation of Materials Physical Chemistry Food Science Nanotechnology and Microengineering
Content Type	Text
Resource Type	Article
Subject	Colloid and Surface Chemistry Materials Chemistry Physical and Theoretical Chemistry Polymers and Plastics

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