NDLI: Studies on morphology of polyaniline films formed at liquid–liquid and solid–liquid interfaces at 25 and 5 °C, respectively, and effect of doping

Content Provider	Springer Nature Link
Author	Waghmode, Babasaheb J. Patil, Sagar H. Jahagirdar, Mandar M. Patil, Virendra S. Waichal, Rupali P. Malkhede, Dipalee D. Sathaye, Shivaram D. Patil, Kashinath R.
Copyright Year	2014
Abstract	It is well accepted that the morphology of the nanomaterials has great effect on the properties and hence their applications. Therefore, morphology of materials has become a focus of research in the scientific world. The present study shows that interfacial polymerization and subsequent self-assembly provides a control over the morphology, nanorod/nanosheet, of polyaniline (PANI) films synthesized by liquid–liquid interface reaction technique and solid–liquid interface reaction technique. The synthesized PANI films and its particulate structure are characterized by using various spectroscopic techniques such as UV–visible, ATR-IR, Raman and XPS. The study confirmed the formation, the structure, the size and shape of particles and morphology of PANI by using analytical techniques namely, SAED, SEM and TEM. An important observation is that doping with HCl significantly improves the nanorod formation at the interface. The doped PANI electrode exhibits a higher area with rectangular shape in CV cycle and better cycle stability when compared with the performance of undoped PANI films. We believe that the results of these studies can give valuable leads to manoeuvre formation of PANI films with desired morphology for various applications. Figure Time and temperature-dependent morphology of PANI layer leading to the formation of one/two-dimensional structures namely, PANI rods/sheets, is achieved by monitoring of self-assembly of nano particulate film formed at liquid–liquid/solid–liquid interfaces
Starting Page	1079
Ending Page	1089
Page Count	11
File Format	PDF
ISSN	0303402X
Journal	Colloid and Polymer Science
Volume Number	292
Issue Number	5
e-ISSN	14351536
Language	English
Publisher	Springer Berlin Heidelberg
Publisher Date	2014-01-15
Publisher Place	Berlin/Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Polyaniline Thin films Liquid–liquid interface Solid–liquid interface Nanorods Nanosheets Self-assembly Interfacial polymerization Polymer Sciences Soft and Granular Matter, Complex Fluids and Microfluidics Characterization and Evaluation of Materials Physical Chemistry Food Science Nanotechnology and Microengineering
Content Type	Text
Resource Type	Article
Subject	Colloid and Surface Chemistry Materials Chemistry Physical and Theoretical Chemistry Polymers and Plastics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Janus nanosheets by emulsion interfacial crosslinking of reactive surfactants

Electrochemical property of graphene oxide/polyaniline composite prepared by in situ interfacial polymerization

One-pot interfacial polymerization to prepare PolyHIPEs with functional surface

Morphology and conductivity tuning of polyaniline using short-chain alcohols by heterophase polymerization

Polytriphenylamines synthesized by interfacial and microemulsion oxidative polymerization

Enhancement of polyaniline’s electrical conductivity by coagulation polymerization

Self-assembly of aniline oligomers in aqueous medium

Facile preparation of α-Fe2O3/carbon and polyhydroxy iron cation/polyaniline hollow particles

Polyaniline precipitation in aqueous medium: from bulk aggregates to nanoparticles

Studies on morphology of polyaniline films formed at liquid–liquid and solid–liquid interfaces at 25 and 5 °C, respectively, and effect of doping

Similar Documents

Janus nanosheets by emulsion interfacial crosslinking of reactive surfactants

Electrochemical property of graphene oxide/polyaniline composite prepared by in situ interfacial polymerization

One-pot interfacial polymerization to prepare PolyHIPEs with functional surface

Morphology and conductivity tuning of polyaniline using short-chain alcohols by heterophase polymerization

Polytriphenylamines synthesized by interfacial and microemulsion oxidative polymerization

Enhancement of polyaniline’s electrical conductivity by coagulation polymerization

Self-assembly of aniline oligomers in aqueous medium

Facile preparation of α-Fe2O3/carbon and polyhydroxy iron cation/polyaniline hollow particles

Polyaniline precipitation in aqueous medium: from bulk aggregates to nanoparticles

Studies on morphology of polyaniline films formed at liquid–liquid and solid–liquid interfaces at 25 and 5 °C, respectively, and effect of doping