NDLI: Apodized 2f/1f wavelength modulation spectroscopy method for calibration-free trace detection of carbon monoxide in the near-infrared region: theory and experiment

Content Provider	Springer Nature Link
Author	Hosseinzadeh Salati, Seyedali Khorsandi, Alireza
Copyright Year	2013
Abstract	We introduce the basics of an apodized 2f/1f wavelength modulation method for the spectroscopy of the R(9) transition line in the first overtone band of carbon monoxide (12C16O) in near-infrared (NIR) region around 2.33 μm. Performance of the method is investigated for high gas concentrations beyond the optically thin limit to generalize common 2f/1f wavelength modulation spectroscopy (WMS) reported by Rieker et al. (Appl Opt 48:5546, [28]). Numerical simulations are performed based on real experimental parameters associated with a NIR spectrometer designed in our laboratory. The results primarily show a more linear response and less error than occurred in the common WMS-2f/1f method for an optically thick sample. It is also theoretically shown that the apodized method enables sharpening the spectrum without peak displacement compared to the common WMS-2f/1f method. The validity of the method is verified experimentally by the trace detection of an air-broadened R(9) CO absorption line centered at 4,294.637 cm−1 at atmospheric pressure and room temperature. The effect of a so-called scaling k-factor on the sharpening of WMS-2f/1f signal is investigated through trace simulation and detection of CO and methane (CH4) lines in the scanning range of a distributed feedback laser. The obtained results show very good agreement between simulation and experiment.
Starting Page	521
Ending Page	531
Page Count	11
File Format	PDF
ISSN	09462171
Journal	Applied Physics B
Volume Number	116
Issue Number	3
e-ISSN	14320649
Language	English
Publisher	Springer Berlin Heidelberg
Publisher Date	2013-11-26
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Physics Physical Chemistry Laser Technology, Photonics Quantum Optics Optics, Optoelectronics, Plasmonics and Optical Devices Engineering
Content Type	Text
Resource Type	Article
Subject	Physics and Astronomy

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