NDLI: Eu3+ luminescence and Gd3+-Eu3+ energy transfer in K5Li2GdF10:Eu3+

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Eu3+ luminescence and Gd3+-Eu3+ energy transfer in K5Li2GdF10:Eu3+

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Eu3+ luminescence and Gd3+-Eu3+ energy transfer in K5Li2GdF10:Eu3+

Content Provider	Springer Nature Link
Author	Ryba Romawski, W. Gołvab, S. Dominiak Dzik, G. Solarz, P.
Copyright Year	2001
Abstract	Polycrystalline samples of europium-doped K5Li2GdF10 have been obtained by a slow cooling of melted compound and investigated using spectroscopy methods. Luminescence from the 5 D 2 level of Eu3+ is found to be weak. Intense visible emission upon excitation into the 5 D 2 or higher energy levels has been attributed to overlapping transitions from long-lived 5 D 1 and 5 D 0 levels. A strong increase of the 5 D 0 emission at the expense of the 5 D 1 emission occurs between 5 K and 25 K without significant change of the 5 D 1 lifetime. To account for this, it is supposed that both the radiative and the nonradiative transition rates are temperature-dependent. Efficient energy transfer from the 6 G J levels of Gd3+ to Eu3+ ions has been evidenced by excitation spectra in the VUV region and VUV-excited luminescence. It has been concluded that the cross relaxation contributes to the energy-transfer process.
Starting Page	581
Ending Page	586
Page Count	6
File Format	PDF
ISSN	09478396
Journal	Applied Physics A
Volume Number	74
Issue Number	4
e-ISSN	14320630
Language	English
Publisher	Springer-Verlag
Publisher Date	2002-04-01
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Science

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