NDLI: Simplified TERP to achieve living free radical polymerization with crude ethyl 2-phenyltellanyl-2-methylpropionate as mediator

Content Provider	Springer Nature Link
Author	Chen, Haochuan Jiao, Jiao Zhao, Changwen Ma, Yuhong Ma, Wenchao Yang, Wantai
Copyright Year	2014
Abstract	Organotellurium compounds-mediated living radical polymerization (TERP) is one of the most robust tools of living free radical polymerizations (LRP). However, synthesis and purification of organotellurium compounds are time-consuming and to be operated in an inert atmosphere due to their extreme sensitivity to trace oxygen. In this article, a simple process of TERP, operating in open air, has been reported. It has demonstrated that the crude organotellurium compound, ethyl 2-phenyltellanyl-2-methylpropionate, could mediate 2,2′-azobis (isobutyronitrile) initiated styrene (St) and butyl acrylate (BA) polymerization as an LRP system. For the bulk and solution polymerization of St and the solution polymerization of BA, the molecular weights of produced polymers increased linearly with the monomer conversions. During the same time, the molecular weight distributions kept under 1.3. The UV–vis spectrum showed that the PS polymer chain bearing C-TePh end group. With the sequential monomer addition technique, a clean diblock polymer of PS-b-PBA was also obtained.
Starting Page	1797
Ending Page	1811
Page Count	15
File Format	PDF
ISSN	01700839
Journal	Polymer Bulletin
Volume Number	71
Issue Number	7
e-ISSN	14362449
Language	English
Publisher	Springer Berlin Heidelberg
Publisher Date	2014-04-13
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Living free radical polymerization Chain transfer agent Organotellurium compound Styrene Butyl acrylate Block copolymer Polymer Sciences Soft and Granular Matter, Complex Fluids and Microfluidics Characterization and Evaluation of Materials Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry Condensed Matter Physics Polymers and Plastics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Emulsifier-free, organotellurium-mediated living radical emulsion polymerization (emulsion TERP) of styrene: poly(dimethylaminoethyl methacrylate) macro-TERP agent

Effect of stirring rate on particle formation in emulsifier-free, organotellurium-mediated living radical emulsion polymerization (emulsion TERP) of styrene

Nitroxide-mediated photo-controlled/living radical polymerization of ethyl acrylate

A kinetic study of free radical copolymerization of styrene/butyl acrylate

Soap-free emulsion polymerization of n-butyl acrylate in aqueous solution in the presence of α- and methylated β-cyclodextrin

Polystyrene-block-poly(butyl acrylate) and polystyrene-block-poly[(butyl acrylate)-co-styrene] block copolymers prepared via controlled free-radical miniemulsion polymerization using degenerative iodine transfer

Convenient synthesis of a surface-active alkoxyamineinitiator from styrene oxide Living/free-radical polymerization of styrene and n-butyl acrylate

Organotellurium-mediated living radical polymerization under photoirradiation by a low-intensity light-emitting diode

A kinetic study of butyl acrylate free radical polymerization in benzene solution

Simplified TERP to achieve living free radical polymerization with crude ethyl 2-phenyltellanyl-2-methylpropionate as mediator

Similar Documents

Emulsifier-free, organotellurium-mediated living radical emulsion polymerization (emulsion TERP) of styrene: poly(dimethylaminoethyl methacrylate) macro-TERP agent

Effect of stirring rate on particle formation in emulsifier-free, organotellurium-mediated living radical emulsion polymerization (emulsion TERP) of styrene

Nitroxide-mediated photo-controlled/living radical polymerization of ethyl acrylate

A kinetic study of free radical copolymerization of styrene/butyl acrylate

Soap-free emulsion polymerization of n-butyl acrylate in aqueous solution in the presence of α- and methylated β-cyclodextrin

Polystyrene-block-poly(butyl acrylate) and polystyrene-block-poly[(butyl acrylate)-co-styrene] block copolymers prepared via controlled free-radical miniemulsion polymerization using degenerative iodine transfer

Convenient synthesis of a surface-active alkoxyamineinitiator from styrene oxide Living/free-radical polymerization of styrene and n-butyl acrylate

Organotellurium-mediated living radical polymerization under photoirradiation by a low-intensity light-emitting diode

A kinetic study of butyl acrylate free radical polymerization in benzene solution

Simplified TERP to achieve living free radical polymerization with crude ethyl 2-phenyltellanyl-2-methylpropionate as mediator