NDLI: Hansen solubility parameters of cellulose acetate butyrate–poly(caprolactone) diol blend by inverse gas chromatography

Content Provider	Springer Nature Link
Author	Ramanaiah, S. Reddy, A. Sudharshan Reddy, K. S.
Copyright Year	2012
Abstract	The specific retention volumes, $$ V_{\text{g}}^{0} $$ , for adsorption of 21 solute probes on the solid surface of cellulose acetate butyrate (CAB)–poly(caprolactone) diol (PCLD) blend determined in the temperature range by inverse gas chromatography were used to evaluate Hansen solubility parameters (HSP). The effect of plasticizer, PCLD, on the HSP of CAB was investigated. The three components of HSP namely dispersive $$ \delta_{2}^{\text{d}} $$ , polar $$ \delta_{2}^{\text{p}} $$ , and hydrogen bonding $$ \delta_{2}^{\text{h}} $$ of the blend surface were compared with the CAB surface. The $$ \delta_{2}^{\text{h}} $$ of CAB was increased due to the addition of PCLD, while the change in the dispersive and polar components was found to be insignificant. The three HSP were decreasing linearly with increase of temperature for the blend as well as for pure CAB. The variation of HSP with weight fraction of CAB shown that the $$ \delta_{2}^{\text{p}} $$ was positively deviating from linearity whereas $$ \delta_{2}^{\text{d}} $$ and $$ \delta_{2}^{\text{h}} $$ were negatively deviating from linearity.
Starting Page	1303
Ending Page	1312
Page Count	10
File Format	PDF
ISSN	01700839
Journal	Polymer Bulletin
Volume Number	70
Issue Number	4
e-ISSN	14362449
Language	English
Publisher	Springer-Verlag
Publisher Date	2012-09-22
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Cellulose acetate butyrate–poly(caprolactone) diol blend Inverse gas chromatography Hansen solubility parameters Polymer Sciences Soft and Granular Matter, Complex Fluids and Microfluidics Characterization and Evaluation of Materials Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry Condensed Matter Physics Polymers and Plastics

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