NDLI: Synthesis, characterization, and aqueous solution behavior of copolymers of acrylamide and sodium 10-acryloyloxydecanoate

Content Provider	Springer Nature Link
Author	Song, Chunlei An, Huiyong Yang, Qingbo Li, Wenbo Liu, Chang Wang, Pixin
Copyright Year	2011
Abstract	A new water-soluble monomer of sodium 10-Acryloyloxydecanoate (NaAD), which possesses a hydrophobic group and an ionizable group, was synthesized from acryloyl chloride and 10-hydroxydecanoic acid, and the series of copolymers of NaAD with acrylamide (AM) were prepared by the free radical polymerization in aqueous solution using ammonium persulfate as the initiator. The feed ratio of NaAD:AM was varied from 5:95 to 70:30 mol%, with the total monomer concentration held constant at 0.5 M. The copolymer compositions were determined from elemental analysis. The molecular weights of the copolymers were determined by gel permeation chromatography ranged from 0.76 × 106 to 1.37 × 106 g/mol. All copolymers were soluble in deionized water and salt solutions at pH > 5. The dilute and semidilute solution behavior of the copolymers was studied as a function of composition, pH, and added electrolytes, and the results indicated that NaAD30 exhibited much higher viscosity values. At moderate pH values, the copolymers coils become slightly more expanded and intermolecular association interactions occur, which was indicated by fluorescence and apparent viscosity measurements. Upon the addition of NaCl and in low pH, viscosities tended to decrease because of the disruption of the intermolecular associations.
Starting Page	1917
Ending Page	1934
Page Count	18
File Format	PDF
ISSN	01700839
Journal	Polymer Bulletin
Volume Number	67
Issue Number	9
e-ISSN	14362449
Language	English
Publisher	Springer-Verlag
Publisher Date	2011-07-29
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Sodium 10-acryloyloxydecanoate Rheology Viscosity Water-soluble polymers Solution properties Polymer Sciences Physical Chemistry Characterization and Evaluation of Materials Soft and Granular Matter, Complex Fluids and Microfluidics
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry Condensed Matter Physics Polymers and Plastics

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