NDLI: Thermo-oxidative stability of poly(methyl methacrylate)/poly(methyl methacrylate)-grafted SiO2 nanocomposites

Content Provider	Springer Nature Link
Author	Li, Deling Su, Guixian He, Qin Zhang, Qing Liu, Lihua
Copyright Year	2013
Abstract	Thermo-oxidative stability of PMMA-grafted SiO2 and PMMA/PMMA-grafted SiO2 nanocomposites was investigated by conventional non-isothermal gravimetric technique. It was interesting to find that PMMA-grafted SiO2 nanoparticles exhibited higher thermo-oxidative stability than that of PMMA. The apparent activation energy of PMMA-grafted SiO2 nanoparticles increased with the grafting ratio of PMMA from SiO2, which was estimated by Kissinger method. This indicates that the strong interactions existing between the grafted chains are responsible for the enhanced thermo-oxidative stability of PMMA-grafted SiO2 nanoparticles. However, the grafting ratio of PMMA from SiO2 in nanoparticles has only limited effect on the thermo-oxidative stability of PMMA/PMMA-grafted SiO2 nanocomposites due to a much lower content of grafted PMMA in the nanoparticles relative to PMMA. The increased thermo-oxidative stability of PMMA/PMMA-grafted SiO2 nanocomposites is possibly resulted from the increased SiO2 content in the nanocomposites, in which the grafting ratio of PMMA in PMMA-grafted SiO2 nanoparticles is kept almost as a constant. The glass transition temperature (T g) of PMMA/PMMA-grafted SiO2 nanocomposites is about 25 °C and is higher than that of PMMA. The grafting ratio of PMMA from SiO2 in the nanoparticles has no qualitative effects on the T g of the nanocomposites.
Starting Page	487
Ending Page	496
Page Count	10
File Format	PDF
ISSN	01700839
Journal	Polymer Bulletin
Volume Number	71
Issue Number	2
e-ISSN	14362449
Language	English
Publisher	Springer Berlin Heidelberg
Publisher Date	2013-11-15
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Poly(methyl methacrylate) Nanocomposite Thermo-oxidative stability Thermogravimetry Kinetics Polymer Sciences Soft and Granular Matter, Complex Fluids and Microfluidics Characterization and Evaluation of Materials Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry Condensed Matter Physics Polymers and Plastics

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