NDLI: Physicochemical characterization of titanium dioxide pigments using various techniques for size determination and asymmetric flow field flow fractionation hyphenated with inductively coupled plasma mass spectrometry

Please wait, while we are loading the content...

Determination of eugenol in fish and shrimp muscle tissue by stable isotope dilution assay and solid-phase extraction coupled gas chromatography–triple quadrupole mass spectrometry

Contaminant screening of wastewater with HPLC-IM-qTOF-MS and LC+LC-IM-qTOF-MS using a CCS database

Aminophenylboronic acid polymer nanoparticles for quantitation of glucose and for insulin release

Systematic comparison of static and dynamic headspace sampling techniques for gas chromatography

Measurement of the viscoelastic properties of blood plasma clot formation in response to tissue factor concentration-dependent activation

Physical and chemical characterization of cerium(IV) oxide nanoparticles

Analysis of diterpenic compounds by GC-MS/MS: contribution to the identification of main conifer resins

Rapid simultaneous analysis of 17 haloacetic acids and related halogenated water contaminants by high-performance ion chromatography-tandem mass spectrometry

Profile and quantification of human stratum corneum ceramides by normal-phase liquid chromatography coupled with dynamic multiple reaction monitoring of mass spectrometry: development of targeted lipidomic method and application to human stratum corneum of different age groups

Effect of charge on the conformation of highly basic peptides including the tail regions of histone proteins by ion mobility mass spectrometry

Identification of fungal metabolites from inside Gallus gallus domesticus eggshells by non-invasively detecting volatile organic compounds (VOCs)

Nano selenium as antioxidant agent in a multilayer food packaging material

Using activated attapulgite as sorbent for solid-phase extraction of melamine in milk formula samples

Physicochemical characterization of titanium dioxide pigments using various techniques for size determination and asymmetric flow field flow fractionation hyphenated with inductively coupled plasma mass spectrometry

Online coupling solid-phase ligand-fishing with high-performance liquid chromatography–diode array detector–tandem mass spectrometry for rapid screening and identification of xanthine oxidase inhibitors in natural products

Lateral flow biosensor for multiplex detection of nitrofuran metabolites based on functionalized magnetic beads

A facile label-free aptasensor for detecting ATP based on fluorescence enhancement of poly(thymine)-templated copper nanoparticles

Enantioselective determination of the chiral pesticide isofenphos-methyl in vegetables, fruits, and soil and its enantioselective degradation in pak choi using HPLC with UV detection

An approach to optimize sample preparation for MALDI imaging MS of FFPE sections using fractional factorial design of experiments

The development of plasma pseudotargeted GC-MS metabolic profiling and its application in bladder cancer

Parallel-processing continuous-flow device for optimization-free polymerase chain reaction

Novel diffusive gradients in thin films technique to assess labile sulfate in soil

Molecularly imprinted polymer nanoparticles-based electrochemical sensor for determination of diazinon pesticide in well water and apple fruit samples

Photosensitive diazotized poly(ethylene glycol) covalent capillary coatings for analysis of proteins by capillary electrophoresis

SFC-MS/MS as an orthogonal technique for improved screening of polar analytes in anti-doping control

The determination of 22 natural brassinosteroids in a minute sample of plant tissue by UHPLC–ESI–MS/MS

Extraction of toxic compounds from saliva by magnetic-stirring-assisted micro-solid-phase extraction step followed by headspace-gas chromatography-ion mobility spectrometry

Determination of type A trichothecenes in coix seed by magnetic solid-phase extraction based on magnetic multi-walled carbon nanotubes coupled with ultra-high performance liquid chromatography-tandem mass spectrometry

Application of microwave-assisted extraction and ultra-high performance liquid chromatography–tandem mass spectrometry for the analysis of sex hormones and corticosteroids in sewage sludge samples

Oxytetracycline recovery from aqueous media using computationally designed molecularly imprinted polymers

Intact lipid imaging of mouse brain samples: MALDI, nanoparticle-laser desorption ionization, and 40 keV argon cluster secondary ion mass spectrometry

Erratum to: Characterization of iodinated disinfection by-products in chlorinated and chloraminated waters using Orbitrap based gas chromatography-mass spectrometry

Analytical and Bioanalytical Chemistry : Volume 408, Issue 23, September 2016

Analytical and Bioanalytical Chemistry : Volume 408, Issue 22, September 2016

Analytical and Bioanalytical Chemistry : Volume 408, Issue 21, August 2016

Analytical and Bioanalytical Chemistry : Volume 408, Issue 19, July 2016

Analytical and Bioanalytical Chemistry : Volume 408, Issue 18, July 2016

Analytical and Bioanalytical Chemistry : Volume 408, Issue 17, July 2016

Analytical and Bioanalytical Chemistry : Volume 408, Issue 16, June 2016

Analytical and Bioanalytical Chemistry : Volume 408, Issue 15, June 2016

Analytical and Bioanalytical Chemistry : Volume 408, Issue 13, May 2016

Analytical and Bioanalytical Chemistry : Volume 397

Analytical and Bioanalytical Chemistry : Volume 391

Analytical and Bioanalytical Chemistry : Volume 380

Analytical and Bioanalytical Chemistry : Volume 379

Analytical and Bioanalytical Chemistry : Volume 378

Analytical and Bioanalytical Chemistry : Volume 373

Physicochemical characterization of titanium dioxide pigments using various techniques for size determination and asymmetric flow field flow fractionation hyphenated with inductively coupled plasma mass spectrometry

Content Provider	Springer Nature Link
Author	Helsper, Johannes P. F. G. Peters, Ruud J. B. Bemmel, Margaretha E. M. Rivera, Zahira E. Herrera Wagner, Stephan Kammer, Frank Tromp, Peter C. Hofmann, Thilo Weigel, Stefan
Copyright Year	2016
Abstract	Seven commercial titanium dioxide pigments and two other well-defined TiO2 materials (TiMs) were physicochemically characterised using asymmetric flow field flow fractionation (aF4) for separation, various techniques to determine size distribution and inductively coupled plasma mass spectrometry (ICPMS) for chemical characterization. The aF4-ICPMS conditions were optimised and validated for linearity, limit of detection, recovery, repeatability and reproducibility, all indicating good performance. Multi-element detection with aF4-ICPMS showed that some commercial pigments contained zirconium co-eluting with titanium in aF4. The other two TiMs, NM103 and NM104, contained aluminium as integral part of the titanium peak eluting in aF4. The materials were characterised using various size determination techniques: retention time in aF4, aF4 hyphenated with multi-angle laser light spectrometry (MALS), single particle ICPMS (spICPMS), scanning electron microscopy (SEM) and particle tracking analysis (PTA). PTA appeared inappropriate. For the other techniques, size distribution patterns were quite similar, i.e. high polydispersity with diameters from 20 to >700 nm, a modal peak between 200 and 500 nm and a shoulder at 600 nm. Number-based size distribution techniques as spICPMS and SEM showed smaller modal diameters than aF4-UV, from which mass-based diameters are calculated. With aF4-MALS calculated, light-scattering-based “diameters of gyration” (Øg) are similar to hydrodynamic diameters (Øh) from aF4-UV analyses and diameters observed with SEM, but much larger than with spICPMS. A Øg/Øh ratio of about 1 indicates that the TiMs are oblate spheres or fractal aggregates. SEM observations confirm the latter structure. The rationale for differences in modal peak diameter is discussed.
Starting Page	6679
Ending Page	6691
Page Count	13
File Format	PDF
ISSN	16182642
Journal	Analytical and Bioanalytical Chemistry
Volume Number	408
Issue Number	24
e-ISSN	16182650
Language	English
Publisher	Springer Berlin Heidelberg
Publisher Date	2016-07-29
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Asymmetric flow field flow fractionation Inductively coupled plasma mass spectrometry Nanomaterials Size distribution Titanium dioxide Zirconium Analytical Chemistry Biochemistry Laboratory Medicine Characterization and Evaluation of Materials Food Science Monitoring/Environmental Analysis
Content Type	Text
Resource Type	Article
Subject	Analytical Chemistry Biochemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Physicochemical characterization of titanium dioxide pigments using various techniques for size determination and asymmetric flow field flow fractionation hyphenated with inductively coupled plasma mass spectrometry.

Sulfur-free Surfactant for Carbide Nanoparticle Characterization in Steel Using Asymmetric Flow Field-Flow Fractionation Hyphenated Inductively Coupled Plasma-Mass Spectrometry.

An improved methodology of asymmetric flow field flow fractionation hyphenated with inductively coupled mass spectrometry for the determination of size distribution of gold nanoparticles in dietary supplements.

Detection and characterization of silver nanoparticles in aqueous matrices using asymmetric-flow field flow fractionation with inductively coupled plasma mass spectrometry.

Characterization and quantification of silver nanoparticles in nutraceuticals and beverages by asymmetric flow field flow fractionation coupled with inductively coupled plasma mass spectrometry.

Size determination and quantification of engineered cerium oxide nanoparticles by flow field-flow fractionation coupled to inductively coupled plasma mass spectrometry.

Investigation of tin adsorption on silica nanoparticles by using flow field-flow fractionation with offline inductively coupled plasma mass spectrometry

Simultaneous on-line detection of SiO2, TiO2 and Al2O3 particles in toothpaste by asymmetric flow field-flow fractionation hyphenated to inductively coupled plasma mass spectrometry

Assessment of the removal of side nanoparticulated populations generated during one-pot synthesis by asymmetric flow field-flow fractionation coupled to elemental mass spectrometry

Physicochemical characterization of titanium dioxide pigments using various techniques for size determination and asymmetric flow field flow fractionation hyphenated with inductively coupled plasma mass spectrometry

Similar Documents

Physicochemical characterization of titanium dioxide pigments using various techniques for size determination and asymmetric flow field flow fractionation hyphenated with inductively coupled plasma mass spectrometry.

Sulfur-free Surfactant for Carbide Nanoparticle Characterization in Steel Using Asymmetric Flow Field-Flow Fractionation Hyphenated Inductively Coupled Plasma-Mass Spectrometry.

An improved methodology of asymmetric flow field flow fractionation hyphenated with inductively coupled mass spectrometry for the determination of size distribution of gold nanoparticles in dietary supplements.

Detection and characterization of silver nanoparticles in aqueous matrices using asymmetric-flow field flow fractionation with inductively coupled plasma mass spectrometry.

Characterization and quantification of silver nanoparticles in nutraceuticals and beverages by asymmetric flow field flow fractionation coupled with inductively coupled plasma mass spectrometry.

Size determination and quantification of engineered cerium oxide nanoparticles by flow field-flow fractionation coupled to inductively coupled plasma mass spectrometry.

Investigation of tin adsorption on silica nanoparticles by using flow field-flow fractionation with offline inductively coupled plasma mass spectrometry

Simultaneous on-line detection of SiO2, TiO2 and Al2O3 particles in toothpaste by asymmetric flow field-flow fractionation hyphenated to inductively coupled plasma mass spectrometry

Assessment of the removal of side nanoparticulated populations generated during one-pot synthesis by asymmetric flow field-flow fractionation coupled to elemental mass spectrometry

Physicochemical characterization of titanium dioxide pigments using various techniques for size determination and asymmetric flow field flow fractionation hyphenated with inductively coupled plasma mass spectrometry