NDLI: Dissipation and Residues of Rimsulfuron in Potato and Soil Under Field Conditions

Content Provider	Springer Nature Link
Author	Wu, Yanbing Liu, Xingang Dong, Fengshou Xu, Jun Zheng, Yongquan
Copyright Year	2012
Abstract	The analytical method for the residue analysis of a sulfonylurea herbicide, rimsulfuron, and its dissipation in soil and potato plants under field conditions were studied. Rimsulfuron residues were determined by Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) method and ultra-performance liquid chromatography coupled with tandem mass spectrometry (UPLC-MS/MS). Mean recoveries ranged from 74.6 % to 106.2 % with relative standard deviations (RSDs) of 2.0 %–13.8 % at three different spiking levels for each different matrix. The limits of detection (LOD) of rimsulfuron were ranged from 0.3 to 1.4 μg/kg, while the limits of quantification (LOQ) ranged from 0.9 to 4.3 μg/kg in different matrixes. The dissipation dynamics of rimsulfuron in the field trials in Shandong and Zhejiang Province were investigated. The half-lives in potato seedlings were 4.1 days in Shandong and 4.3 days in Zhejiang, both with a dissipation rate of 90 % about 7 days after application. The half-lives in soil were 6.0 days in Shandong and 6.6 days in Zhejiang, and with a dissipation rate of 90 % over 28 days. The terminal residues in potato and soil were not detectable. The fact that all the terminal residues were below the maximum residue level (0.1 mg/kg) set by Japan and 0.05 mg/kg set by EU. Hence it was safe for the use of this pesticide and the results also could give a reference for maximum residue limits setting of rimsulfuron in potato in China.
Starting Page	1264
Ending Page	1267
Page Count	4
File Format	PDF
ISSN	00074861
Journal	Bulletin of Environmental Contamination and Toxicology
Volume Number	89
Issue Number	6
e-ISSN	14320800
Language	English
Publisher	Springer-Verlag
Publisher Date	2012-10-18
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Rimsulfuron Potato Residues Dissipation Soil Science & Conservation Ecotoxicology Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution Environmental Chemistry Environmental Health Pollution
Content Type	Text
Resource Type	Article
Subject	Health, Toxicology and Mutagenesis Pollution Medicine Toxicology

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