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Hydroboration and Organic Synthesis: 9-Borabicyclo[3.3.1]nonane (9-BBN)
| Content Provider | Springer-eBooks |
|---|---|
| Author | Dhillon, Ranjit S. |
| Copyright Year | 2007 |
| Abstract | 9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-N, C-S, C-halogen, C-metal and above all C-C bonds. In addition, the suitable substituted / unsaturated R of B-R-9-BBN can be utilized to produce dienes, enynes, allenes etc. with defined stereochemistry. 9-BBN’s derivatives have been elegantly used for the asymmetric reduction of ketone moiety. Diels-Alder and Suzuki reactions have expanded the utility of 9-BBN for the synthesis of a variety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations. |
| File Format | |
| ISBN | 9783540490760 |
| Language | English |
| Publisher | SpringerLink Springer eBooks |
| Access Restriction | Subscribed |
| Subject Keyword | Chemistry Organic Chemistry Medicinal Chemistry Biochemistry, general |
| Content Type | Text |
| Resource Type | Book |