NDLI: Synthesis, Characterization and Liquid Phase Oxidation of Cyclohexane with Hydrogen Peroxide over Oxovanadium(IV) Schiff-base Tetradendate Complex Covalently Anchored to Multi-Wall Carbon Nanotubes (MWNTs)

Please wait, while we are loading the content...

Synthesis, Characterization and Liquid Phase Oxidation of Cyclohexane with Hydrogen Peroxide over Oxovanadium(IV) Schiff-base Tetradendate Complex Covalently Anchored to Multi-Wall Carbon Nanotubes (MWNTs)

Content Provider	Semantic Scholar
Author	Salavati-Niasari, Masoud Bazarganipour, Mehdi
Copyright Year	2009
Abstract	The chemical modification of multi-wall carbon nanotubes (MWNTs) is an emerging area in material science. In the present study, hydroxyl functionalized oxovanadium(IV) Schiff-base; N,N'-bis(4-hydroxysalicylidene)-ethylene-1, 2-diamineoxovanadium(IV), [VO((OH)2-salen)]; has been covalently anchored on modified MWNTs. The new modified MWNTs ([VO((OH)2-salen)]-MWNTs]) have been characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron (XPS), UV-Vis, Diffuse reflectance (DRS), FT-IR spectroscopy and elemental analysis. The analytical data indicated a composition corresponding to the mononuclear complex of tetradentate Schiff-base ligand. The characterization of the data showed the absence of extraneous complex, retention of MWNTs and covalently anchored on modified MWNTs. Liquid-phase oxidation of cyclohexane with H2O2 to a mixture of cyclohexanone, cyclohexanol and cyclohexane-1,2-diol in CH3CN have been reported using oxovanadium(IV) Schiff-base complex covalently anchored on modified MWNTs as catalysts. This catalyst is more selective toward cyclohexanol formation.
Starting Page	355
Ending Page	362
Page Count	8
File Format	PDF HTM / HTML
DOI	10.5012/bkcs.2009.30.2.355
Volume Number	30
Alternate Webpage(s)	http://ocean.kisti.re.kr/downfile/volume/chemical/JCGMCS/2009/v30n2/JCGMCS_2009_v30n2_355.pdf
Alternate Webpage(s)	https://doi.org/10.5012/bkcs.2009.30.2.355
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

Central Library (ISO-9001:2015 Certified)
Indian Institute of Technology Kharagpur
Kharagpur, West Bengal, India | PIN - 721302

See location in the Map
03222 282435
Mail: support@ndl.gov.in

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in