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A dehydrogenative cross-coupling reaction between aromatic aldehydes or ketones and dialkyl H-phosphonates for formyl or acylphenylphosphonates.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Huang, X. H. He, Jian-Shi Huang, Zhi-Zhen |
| Copyright Year | 2015 |
| Abstract | A novel DCC reaction between aromatic aldehydes or ketones and H-phosphonates has been developed for the synthesis of p-formyl or p-acylphenylphosphonates. The synthetic method has excellent para regioselectivities, good yields, and broad substrate scopes and is more benign to the environment. The DCC reaction also tolerates many functional groups, and results in a series of new p-formyl and p-acylphenylphosphonates, which should be important building blocks for the synthesis of versatile arylphosphonate derivatives. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c5ob00161g |
| PubMed reference number | 25773505 |
| Journal | Medline |
| Volume Number | 13 |
| Issue Number | 15 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c5/ob/c5ob00161g/c5ob00161g1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/c5ob00161g |
| Journal | Organic & biomolecular chemistry |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |