I. The analytical applications of 2,2'-pyridilmonoxime. II. The analytical applications of 2,2'-diquinolyl ketoxime.

Content Provider	Semantic Scholar
Author	Stupavsky, Sam
Copyright Year	1971
Abstract	PART I THE ANALYTICAL APPLICATIONS OF 2 , 2 ' PYRIDILMONOXIME The r e a c t io n s o f m eta ls w ith 2 , 2 ' p yrid ilm on ox im e have been s tu d ie d and th e r e a g e n t has been a p p lie d to th e sp e c tr o p h o to m e tr ic d e te r m in a tio n o f p a lla d iu m and c o b a l t . For p a lla d iu m and c o b a l t , th e e f f e c t s due to pH, t im e , s o l v e n t s , r e a g en t c o n c e n tr a t io n and d iv e r s e io n s have been s t u d ie d . The p a lla d iu m and c o b a lt c h e la t e s have been i s o la t e d and c h a r a c te r iz e d . Based upon s p e c t r a l e v id e n c e , th e 2,2* p y r i d i l m o n o x i m e , m.p. 193-194°C, has been a s s ig n e d th e a c o n f ig u r a t io n . PART I I THE ANALYTICAL APPLICATIONS OF 2 , 2 ' DIQUINOLYL KETOXIME The r e a g en t 2 , 2 ' d iq u in o ly l k e to x i m e has been s y n th e s iz e d and i t s r e a c t io n s w ith m e t a l s have been s tu d ie d . I t forms c o l o u r e d w a t e r in s o lu b le com plexes w ith c o b a l t , p a lla d iu m , c o p p e r , g o l d and n i c k e l . The c o b a lt and p a lla d iu m com plexes p o s s e s s e d s u i t a b le a n a l y t i c a l p r o p e r t ie s and p roced u res w ere d e v e lo p e d f o r t h e d e t e r m i n a ­ t i o n o f c o b a lt and p a lla d iu m .
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Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article