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[1,2-Bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-κ2 P,P′][7,8-bis(diphenylphosphino)-7,8-dicarba-nido-undecaborato-κ2 P,P′]gold(I)–dichloromethane–water (2/1/1)
| Content Provider | Semantic Scholar |
|---|---|
| Author | Ioppolo, Joseph A. Clegg, Jack K. Rendina, Louis M. |
| Copyright Year | 2009 |
| Abstract | The title compound, [Au(C(26)H(30)B(10)P(2))(C(26)H(30)B(9)P(2))]·0.5CH(2)Cl(2)·0.5H(2)O, contains two independent complex mol-ecules in the asymmetric unit. The gold(I) centres display a distorted tetra-hedral geometry. The complex is stablized through weak intra-molecular π-π stacking (Cg⋯Cg = 4.17 Å) and edge-to-face inter-actions (H⋯Cg = 3.21 Å). Adjacent mol-ecules inter-act through C-H⋯π (H⋯Cg = 2.88 Å) and B-H⋯π (H⋯Cg = 3.15 Å) contacts, forming a three-dimensional network, with solvent mol-ecules occupying the cavities. One of the phenyl groups was disordered over two sites with occupancy factors of 0.65 and 0.35. |
| Starting Page | m603 |
| Ending Page | m604 |
| Page Count | 2 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S1600536809014937 |
| PubMed reference number | 21583823 |
| Journal | Medline |
| Volume Number | 65 |
| Alternate Webpage(s) | http://ftp.ncbi.nlm.nih.gov/pub/pmc/79/2e/e-65-0m603.PMC2977637.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536809014937 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
