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Unveiling hole trapping and surface dynamics of NiO nanoparticles† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc03442c
| Content Provider | Semantic Scholar |
|---|---|
| Author | D'Amario, Luca Föhlinger, Jens Boschloo, Gerrit Hammarström, Leif |
| Copyright Year | 2018 |
| Abstract | The research effort in mesoporous p-type semiconductors is increasing due to their potential application in photoelectrochemical energy conversion devices. In this paper an electron-hole pair is created by band-gap excitation of NiO nanoparticles and the dynamics of the electron and the hole is followed until their recombination. By spectroscopic characterization it was found that surface Ni3+ states work as traps for both electrons and holes. The trapped electron was assigned to a Ni2+ state and the trapped hole to a "Ni4+" state positioned close to the valence band edge. The recombination kinetics of these traps was studied and related with the concept of hole relaxation suggested before. The time scale of the hole relaxation was found to be in the order of tens of ns. Finally the spectroscopic evidence of this relaxation is presented in a sensitized film. |
| Starting Page | 223 |
| Ending Page | 230 |
| Page Count | 8 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c7sc03442c |
| Alternate Webpage(s) | http://pubs.rsc.org/en/content/articlepdf/2018/sc/c7sc03442c?page=search |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c7/sc/c7sc03442c/c7sc03442c1.pdf |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2018/sc/c7sc03442c |
| PubMed reference number | 29629091 |
| Alternate Webpage(s) | https://doi.org/10.1039/c7sc03442c |
| Journal | Medline |
| Volume Number | 9 |
| Journal | Chemical science |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
