NDLI: Visible-light mediated sulfonylation of thiols via insertion of sulfur dioxide.

Content Provider	Semantic Scholar
Author	Nair, Akshay M. Kumar, Shreemoyee Halder, Indranil Volla, Chandra M. R.
Copyright Year	2019
Abstract	A simple and efficient visible-light mediated synthesis of thiosulfonates via a radical-radical coupling of sulfenyl radicals and arylsulfonyl radicals was developed. The reaction of thiols, aryldiazonium tetrafluoroborates and DABSO proceeded at room temperature using 5 mol% eosin Y. The reaction displayed wide functional group tolerance and delivered the unsymmetrical thiosulfonates in good to excellent yields.
Starting Page	5897
Ending Page	5901
Page Count	5
File Format	PDF HTM / HTML
DOI	10.1039/c9ob01040h
Alternate Webpage(s)	http://www.rsc.org/suppdata/c9/ob/c9ob01040h/c9ob01040h1.pdf
PubMed reference number	31157346
Alternate Webpage(s)	https://doi.org/10.1039/c9ob01040h
Journal	Medline
Volume Number	17
Issue Number	24
Journal	Organic & biomolecular chemistry
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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Visible-light mediated sulfonylation of thiols via insertion of sulfur dioxide.