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Bimetallic mechanism operating in the copolymerization of propylene oxide with carbon dioxide catalyzed by cobalt–salen complexes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Nakano, Koji Hashimoto, Shinichi Nozaki, Kyoko Norma |
| Copyright Year | 2010 |
| Abstract | Dinuclear Co–salen complexes (R,R)-(S,S)-1–4 were synthesized and compared with their mononuclear counterpart rac-5 to suggest that a bimetallic mechanism is in charge for the alternating copolymerization of propylene oxide with CO2 in the absence of onium salt while a monometallic mechanism is more probable in its presence. |
| Starting Page | 369 |
| Ending Page | 373 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C0SC00220H |
| Volume Number | 1 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/sc/c0/c0sc00220h/c0sc00220h.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C0SC00220H |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |