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Lithium ion-crown ether complexes in a molten salt
| Content Provider | Semantic Scholar |
|---|---|
| Author | Eyring, Edward M. Cobranchi, Daryl P. Garland, Ben A. Gerhard, Achim Highley, Aaron M. Huang, Y.-H. Kònya, Gàbor Petrucci, Sergio Eldik, Rudi Van |
| Copyright Year | 1993 |
| Abstract | - Lithium ion forms complexes with crown ethers in a basic, room temperature molten salt. The stability constants of several of these complexes have been determined by lithium-7 NMR measurements. The binary molten salt mixture was 55/45 mole % in 1-methyl-3-ethylimidazolium chloride to aluminum(II1) chloride. Stability constants for 1.: 1 complexes with lithium ion were found to increase in the order 18-crown-6 < 12-crown-4 < benzo-15-crown-5 < 15-crcwn5 in this molten salt at 22 OC. This is the same sequence for lithium ion - crown ether complex stability as was found previously in a 55/45 mole % N-butylpyridinium chloride to aluminum(II1) chloride molten salt. |
| Starting Page | 451 |
| Ending Page | 454 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1351/pac199365030451 |
| Volume Number | 65 |
| Alternate Webpage(s) | http://old.iupac.org/publications/pac/1993/pdf/6503x0451.pdf |
| Alternate Webpage(s) | https://doi.org/10.1351/pac199365030451 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
